Removal of benzotriazole by heterogeneous photoelectro-Fenton like process using ZnFe2O4 nanoparticles as catalyst

被引:51
作者
Wu, Junfeng [1 ,3 ]
Pu, Wenhong [1 ]
Yang, Changzhu [1 ]
Zhang, Man [1 ]
Zhang, Jingdong [2 ]
机构
[1] Huazhong Univ Sci & Technol, Sch Environm Sci & Engn, Wuhan 430074, Peoples R China
[2] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China
[3] Henan Univ Urban Construct, Sch Environm & Municipal Engn, Pingdingshan 467036, Peoples R China
基金
中国国家自然科学基金;
关键词
ZnFe2O4; nanoparticles; photoelectro-Fenton like process; benzotriazole; heterogeneous catalytic degradation; ELECTRO-FENTON; DEGRADATION; MINERALIZATION; OXIDATION; DECOLORIZATION; BEHAVIOR; WATER; DYE; ZN;
D O I
10.1016/S1001-0742(12)60117-X
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
ZnFe2O4 nanoparticles (ZFNPs) were developed as catalyst for the degradation of benzotriazole (BTA) by heterogeneous photoelectro-Fenton (PE-Fenton) like process. ZFNPs were prepared by a co-precipitation process and then characterized with transmission electron microscopy (TEM), X-ray fluorescence (XRF), X-ray diffraction (XRD) and BET surface area. Using such ZFNPs as catalyst, the degradation of BTA was investigated. Due to the high catalytic activity of ZFNPs, PE-Fenton like process showed efficient degradation of BTA. The influencing factors such as pH, dosage of ZFNPs, applied potential and initial concentration of BTA were systematically investigated. Under the optimum conditions, 91.2% of BTA was removed after 180 min treatment.
引用
收藏
页码:801 / 807
页数:7
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