Deep Oxidative Desulfurization of Real Diesel Catalyzed by Na2WO4 in Ionic Liquid

被引:14
|
作者
Liu, D. [1 ]
Gui, J. [1 ]
Liu, D. [1 ]
Peng, X. [1 ]
Yang, S. [1 ]
Sun, Z. [1 ]
机构
[1] Liaoning Shihua Univ, Coll Chem & Mat Sci, Fushun 113001, Liaoning, Peoples R China
关键词
desulfurization; ionic liquid; oxidation; real diesel; tungstate; EXTRACTION; FUELS; ACID;
D O I
10.1080/15567036.2010.503230
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
An effective deep oxidative desulfurization process, catalyzed by Na2WO4 and ionic liquid, was developed for real diesel prehydrotreated. A lower amount of ionic liquid was used, while good catalytic oxidation activity could be obtained under mild conditions. The sulfur content in the real diesel can decrease from the initial 200 to 23.2 ppm after the oxidative desulfurization process, and the sulfur removal rate can reach 88.4%. The catalytic system can be recycled directly after vacuum drying, and there is no obvious change on catalytic activity after recycling five times.
引用
收藏
页码:1 / 8
页数:8
相关论文
共 50 条
  • [1] Oxidative Desulfurization of Diesel Fuel with Hydrogen Peroxide Using Na2WO4 as Catalyst
    Sun Xin
    Long Jun
    Xu Benjing
    Xie Chaogang
    CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY, 2009, (01) : 45 - 50
  • [2] The Deep Oxidative Desulfurization of Fuels Using Na2WO4•2H2O in Acidic Ionic Liquids
    Ge, J.
    Zhou, Y.
    Yang, Y.
    Gao, Q.
    Wu, X.
    Sun, Q.
    PETROLEUM SCIENCE AND TECHNOLOGY, 2013, 31 (21) : 2280 - 2286
  • [3] Oxidation of dibenzothiophene catalyzed by Na2WO4 in a halogen-free ionic liquid
    Dan Liu
    Jianzhou Gui
    Jianfeng Ding
    JuanJuan Ma
    Juyoung Lee
    Zhaolin Sun
    Reaction Kinetics, Mechanisms and Catalysis, 2011, 104 : 111 - 123
  • [4] Oxidation of dibenzothiophene catalyzed by Na2WO4 in a halogen-free ionic liquid
    Liu, Dan
    Gui, Jianzhou
    Ding, Jianfeng
    Ma, JuanJuan
    Lee, Juyoung
    Sun, Zhaolin
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2011, 104 (01) : 111 - 123
  • [5] Study of oxidative desulfurization of diesel catalyzed by acidic ionic liquid
    College of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001, China
    Ranliao Huaxue Xuebao J. Fuel Chem. Technol., 2008, 5 (601-605): : 601 - 605
  • [6] Deep oxidative desulfurization catalyzed by an ionic liquid-type peroxotungsten catalystDeep oxidative desulfurization catalyzed by an ionic liquid-type peroxotungsten catalyst
    Chen, Jizhong
    Chen, Chen
    Zhang, Ran
    Guo, Li
    Hua, Li
    Chen, Angjun
    Xiu, Yuhe
    Liu, Xuerui
    Hou, Zhenshan
    RSC ADVANCES, 2015, 5 (33): : 25904 - 25910
  • [7] Gibbs energy of formation of Na2WO4 and Na3WO4 in liquid sodium
    Bhat, NP
    Borgstedt, HU
    JOURNAL OF NUCLEAR MATERIALS, 1997, 244 (01) : 59 - 65
  • [8] Gibbs energy of formation of Na2WO4 and Na3WO4 in liquid sodium
    Indira Gandhi Cent for Atomic, Research, Kalpakkam, India
    J Nucl Mater, 1 (59-65):
  • [9] Elementary reactions in the oxidative coupling of methane over Mn/Na2WO4/SiO2 and Mn/Na2WO4/MgO catalysts
    Pak, S
    Qiu, P
    Lunsford, JH
    JOURNAL OF CATALYSIS, 1998, 179 (01) : 222 - 230
  • [10] METHANE OXIDATIVE COUPLING OVER NA2WO4/SIO2
    YAN, QJ
    WANG, Y
    JIN, YS
    CHEN, Y
    CATALYSIS LETTERS, 1992, 13 (03) : 221 - 228