Thermal and photoinduced valence tautomerism of a chain compound

被引：17

作者：

Chen LiQin ^{[1
]}

Wei RongJia ^{[1
]}

Tao Jun ^{[1
]}

Huang RongBin ^{[1
]}

Zheng LanSun ^{[1
]}

机构：

[1] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2012年 / 55卷 / 06期

基金：

中国国家自然科学基金;

关键词：

valence tautomerism; coordination polymer; cobalt(II); photo excitation; ELECTRON-TRANSFER; INTERCONVERSION; TRANSITION; HYSTERESIS; COMPLEXES; LIGAND;

D O I：

10.1007/s11426-011-4484-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein reported is an example of one-dimensional coordination polymer [Co-II(3,5-DBsq)(2)(dpg)]center dot(3,5-H(2)DBcat)(2) (1) (3,5-DBsq = 3,5-di-tert-butylsemiquinonate, 3,5-H(2)DBcat = 3,5-di-tert-butyl-benzene-1,2-diol, dpg = meso-alpha,beta-di(4-pyridyl)glycol) capable of undergoing thermal and photoinduced valence tautomeric transitions.

引用

页码：1037 / 1041

页数：5

共 23 条

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