Ion Transport to the Interior of Metal-Organic Pyrogallol[4]arene Nanocapsules

被引:43
|
作者
Jin, Ping [2 ]
Dalgarno, Scott J. [1 ]
Barnes, Charles [2 ]
Teat, Simon J. [3 ]
Atwood, Jerry L. [2 ]
机构
[1] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland
[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
[3] Adv Light Source, Berkeley Lab, Berkeley, CA 94720 USA
基金
美国国家科学基金会;
关键词
D O I
10.1021/ja807983t
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal ions or ion pairs (silver nitrate shown) are transported to the interior of metal-organic pyrogallol[4]arene nanocapsules via aqueous "gates". This transport has been studied by X-ray crystallography and shows the affinity of the ions to reside deep in the polyaromatic regions of the assemblies.
引用
收藏
页码:17262 / +
页数:3
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