Some Key Features to Consider When Studying Acrylamide-Based Polymers for Chemical Enhanced Oil Recovery

被引:82
作者
Thomas, A. [1 ]
Gaillard, N. [1 ]
Favero, C. [1 ]
机构
[1] SNF SAS, ZAC Milieux, F-42163 Andrezieux Boutheon, France
来源
OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES | 2012年 / 67卷 / 06期
关键词
PARTIALLY HYDROLYZED POLYACRYLAMIDE; AQUEOUS-SOLUTION; DEGRADATION; VISCOSITY;
D O I
10.2516/ogst/2012065
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Among Chemical Enhanced Oil Recovery (CEOR) methods, polymer flooding is a straightforward technique with a long commercial history and proven results. It consists in injecting polymer-augmented water into a subterranean formation in order to improve, thanks to the viscosity increase, the sweep efficiency in the reservoir and provides a mobility control between water and the hydrocarbons. However, implementing successfully a polymer flood in the field requires specific know-how to avoid polymer degradation and associated viscosity loss. The first stage begins with the selection of the right polymer for the reservoir, depending on the water quality, temperature, permeability and presence of contaminants such as iron, hydrogen sulfide and oxygen. Several laboratory tests have to be performed to ensure the long term stability of the product as well as core flooding experiments to check parameters such as injectivity and propagation through the porous medium. The next step is the design and selection of equipment for the dissolution and the injection of the polymer solution into the reservoir. Surface facilities are paramount for the quality of the injected solution: the goal is to allow a good hydration, maturation and transport of the solution while avoiding any type of degradation that can occur either chemically (oxygen ingress) or mechanically (chokes, centrifugal pumps). Another aspect that can be assessed is the degradation of the back-produced polymer. Several studies have shown that there is no influence of the polymer on the separation of crude and water; the polymer being water-soluble. However, when the viscosity of the produced water is above 4 mPa.s, a treatment may be operated before the water treatment process to avoid any difficulty in the surface facilities and an optimum efficiency.
引用
收藏
页码:887 / 902
页数:16
相关论文
共 30 条
[1]  
BORTHAKUR A, 1995, RES IND, V40, P90
[2]  
Doe P.H., 1987, SPE RESERVOIR ENG, V2, P461, DOI [10.2118/14233-PA, DOI 10.2118/14233-PA]
[3]  
ELLWANGER RE, 1980, POLYM BULL, V3, P369, DOI 10.1007/BF00255097
[4]  
Fenton H. J. H., 1894, J CHEM SOC, V65, P899, DOI [DOI 10.1039/CT8946500899, 10.1039/ct8946500899]
[5]  
Fernandez I. J., 2005, SPE INT S OILF CHEM
[6]  
Gaillard N., 2010, SPE IMPR OIL REC S T
[7]   FREE RADICAL-INDUCED OXIDATIVE-DEGRADATION OF POLYACRYLAMIDE IN AQUEOUS-SOLUTION [J].
GROLLMANN, U ;
SCHNABEL, W .
POLYMER DEGRADATION AND STABILITY, 1982, 4 (03) :203-212
[8]   WATER-SOLUBLE POLYMERS FOR HOSTILE ENVIRONMENT ENHANCED OIL-RECOVERY APPLICATIONS [J].
HSIEH, HL ;
MORADIARAGHI, A ;
STAHL, GA ;
WESTERMAN, IJ .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1992, 64 :121-135
[9]   EFFECT OF ADDITIVES ON THE DEGRADATION OF ACRYLAMIDE ACRYLIC-ACID COPOLYMER IN AQUEOUS-SOLUTION [J].
KHERADMAND, H ;
FRANCOIS, J ;
PLAZANET, V .
JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 39 (09) :1847-1857
[10]  
Kulawardana E., 2012, 18 SPE IMPR OIL REC