Ionic liquid green synthesis of CeO2 nanorods and nano-cubes: Investigation of the shape dependent on catalytic performance

被引:22
作者
Alhumaimess, Mosaed [1 ]
Aldosari, Obaid [2 ,3 ]
Alshammari, Hamed [4 ]
Kamel, Mahmoud M. [1 ]
Betiha, Mohamed A. [5 ]
Hassan, Hassan M. A. [1 ,6 ]
机构
[1] Jouf Univ, Coll Sci, Dept Chem, POB 2014, Sakaka, Saudi Arabia
[2] Majmaah Univ, Coll Sci & Human Studies Hautat Sudair, Dept Chem, Majmaah, Saudi Arabia
[3] Prince Sattam bin Abdulaziz Univ, Coll Sci & Humanities, Dept Chem, Alkharj, Saudi Arabia
[4] Hail Univ, Fac Sci, Dept Chem, POB 2440, Hail 81451, Saudi Arabia
[5] Egyptian Petr Res Inst, Nasr City 11727, Egypt
[6] Suez Univ, Fac Sci, Dept Chem, Suez, Egypt
关键词
CO oxidation; Epoxidation; Ionic liquids; CeO2 nano-cubes CeO2 nano-rods; Au/CeO2; VAPOR-PHASE SYNTHESIS; CARBON NANOTUBES; NANOCOMPOSITE MATERIALS; NANOPARTICLE CATALYSTS; CERIA NANOPARTICLES; MICROWAVE SYNTHESIS; CDS NANOCRYSTALS; CO OXIDATION; NANOWIRES; EFFICIENT;
D O I
10.1016/j.molliq.2019.02.014
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new facile and scalable approach for utilizing basic ionic liquid, 1-butyl-3-methylimidazolium hydroxide ([BMIM]+OH-) for the fabrication of different shapes of ceria nanostructures was adopted. The features of the fabricated ceria and their corresponding gold nanocatalysts were characterized by employing ICP, HRTEM, XRD, XPS, BET and UV-vis spectroscopy. Catalytic performance of CeO2 and its dependence on shape was studied in the oxidation of CO and olefins epoxidation. The ratio between the ionic liquid and cerium precursor is one of the valuable factors used to monitor the growth of the particles. The catalytic performance of ceria was found to be dependent on the morphology of the catalysts. The catalytic performance of CeO2 in the form of nanorod-shapes is better than that of nanocubes and bulk. The deposition of gold nanoparticles on different shaped CeO2 much enhanced their catalytic performance. This enhancement in catalytic performance was, however, more significant in the case of rod-shaped ceria. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:649 / 656
页数:8
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