Synthesis and reactivity of 2-(2-thienyl)phenanthro[9,10-d]oxazole

被引：0
|
作者：
Aleksandrov, A. A. [1 ]
El'chaninov, M. M. [1 ]
机构：
[1] Platov South Russian State Polytech Univ, Novocherkassk 346428, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 08期
基金：
俄罗斯科学基金会;
关键词：
9,10-phenanthrene quinone; thiophene-2-carbaldehyde; 2-(2-thienyl) phenanthro[9,10-d]imidazole; electrophilic substitution; thiophene; phenanthrene;
D O I：
10.1134/S1070363215080125
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2-(2-Thienyl)phenanthro[9,10-d]oxazole has been synthesized via reaction of 9,10-phenanthrene quinone imine with thiophene-2-carbaldehyde in ethanol. The product interaction with electrophilic reagents (nitration, bromination, sulfonation, formylation, acylation) has been studied. Electrophilic attack takes place at the thiophene ring or at phenanthrene moiety, depending on the reaction conditions.
引用
收藏
页码：1862 / 1865
页数：4
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