Synthesis and reactivity of 2-(2-thienyl)phenanthro[9,10-d]oxazole

被引：0
|
作者：
Aleksandrov, A. A. [1 ]
El'chaninov, M. M. [1 ]
机构：
[1] Platov South Russian State Polytech Univ, Novocherkassk 346428, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 08期
基金：
俄罗斯科学基金会;
关键词：
9,10-phenanthrene quinone; thiophene-2-carbaldehyde; 2-(2-thienyl) phenanthro[9,10-d]imidazole; electrophilic substitution; thiophene; phenanthrene;
D O I：
10.1134/S1070363215080125
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2-(2-Thienyl)phenanthro[9,10-d]oxazole has been synthesized via reaction of 9,10-phenanthrene quinone imine with thiophene-2-carbaldehyde in ethanol. The product interaction with electrophilic reagents (nitration, bromination, sulfonation, formylation, acylation) has been studied. Electrophilic attack takes place at the thiophene ring or at phenanthrene moiety, depending on the reaction conditions.
引用
收藏
页码：1862 / 1865
页数：4
相关论文
共 50 条
  • [31] Crystal Structure of 1-Ethyl-2-(2-nitrophenyl)-phenanthro[9,10-d]imidazole
    Goro Yasuda
    Hisashi Morikawa
    Hiroshi Kimoto
    Analytical Sciences, 1997, 13 : 1053 - 1054
  • [32] New bipolar host materials using Phenanthro[9,10-d]oxazole moiety for highly efficient red phosphorescence
    Kang, Seokwoo
    Park, So-Ra
    Suh, Min Chul
    Park, Jongwook
    DYES AND PIGMENTS, 2020, 174
  • [33] 2-(2-aminophenylthio)-2-(2-thienyl)ethyl 2-thienyl cetone
    Morgant, G
    Labouze, X
    Viossat, B
    Lancelot, JC
    Dung, NH
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1996, 52 : 923 - 925
  • [34] 2-(2-Aminophenylthio)-2-(2-thienyl)ethyl 2-thienyl cetone
    Universite de Paris-Sud, Chatenay-Malabry, France
    Acta Crystallogr Sect C Cryst Struct Commun, Pt 4 (923-925):
  • [35] Substitution reactions of phenanthro[9,10-d]triazole with benzyl chlorides
    Yasuda, G
    Kimoto, H
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1998, 35 (02) : 365 - 369
  • [36] Photochemical Conversion of Phenanthro[9,10-d]imidazoles into π-Expanded Heterocycles
    Skonieczny, Kamil
    Gryko, Daniel T.
    JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (11): : 5753 - 5763
  • [37] Synthesis and reactivity of 2-(2-thienyl)oxazolo[4,5-b]pyridine
    Aleksandrov, A. A.
    El'chaninov, M. M.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2015, 85 (04) : 858 - 860
  • [38] PROTONATION OF 2-(2-THIENYL)PYRROLE AND 2-(2-THIENYL)-1-VINYLPYRROLES
    SIGALOV, MV
    TROFIMOV, AB
    SHMIDT, EY
    TROFIMOV, BA
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1993, 6 (08) : 471 - 477
  • [39] ELECTROPHILIC AND NUCLEOPHILIC REACTIVITY OF 2-(2-THIENYL)THIENO[2,3-D]PYRIMIDINE
    BOURGUIGNON, J
    MOREAU, M
    QUEGUINER, G
    PASTOUR, P
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE II-CHIMIE MOLECULAIRE ORGANIQUE ET BIOLOGIQUE, 1977, (7-8): : 676 - 682
  • [40] Synthesis and reactivity of 2-(2-thienyl)oxazolo[4,5-b]pyridine
    A. A. Aleksandrov
    M. M. El’chaninov
    Russian Journal of General Chemistry, 2015, 85 : 858 - 860
12345