Studies on cellulose nanocrystals isolated from groundnut shells

被引:228
作者
Bano, Saleheen [1 ]
Negi, Yuvraj Singh [1 ]
机构
[1] Indian Inst Technol, Dept Polymer & Proc Engn, Saharanpur Campus, Roorkee 247001, Saharanpur, India
关键词
Groundnut shells; Cellulose nanocrystals; Static light scattering; THERMAL-STABILITY; EXTRACTION; FIBERS; N; N-DIMETHYLACETAMIDE; NANOCELLULOSE; AGGREGATION; HYDROLYSIS; BEHAVIOR; HUSK;
D O I
10.1016/j.carbpol.2016.10.069
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Today, various renewable biomass resources are accepted as waste material and are mostly burnt or used as cattle feed. The commercial value of these wastes can be increased by utilising them in production of nanomaterials. So, the present work was conducted for isolation of cellulose nanocrystals (CNCs) from groundnut shells which are produced annually as waste in large quantity (similar to 7 million tons). The structural, thermal, morphological & elemental analyses were assessed through corresponding techniques. Light Scattering studies were performed to analyse more likely weight average molecular weight (M-w) & radius of radius (R-g). The high Mw similar to 10(5)g/mol obtained for CNCs in lithium chloride (LiCl)/N,N-dimethylacetamide (DMAc) system, was an interesting feature which gets affected by LiCl and polymer concentrations. Solution with high polymer and low LiCl concentration was found to show higher values of M-w & R-g. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1041 / 1049
页数:9
相关论文
共 41 条
[1]   Flow properties of microcrystalline cellulose suspension prepared by acid treatment of native cellulose [J].
Araki, J ;
Wada, M ;
Kuga, S ;
Okano, T .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1998, 142 (01) :75-82
[2]   Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions [J].
Beck-Candanedo, S ;
Roman, M ;
Gray, DG .
BIOMACROMOLECULES, 2005, 6 (02) :1048-1054
[3]   Analysis of cellulose nanocrystal rod lengths by dynamic light scattering and electron microscopy [J].
Boluk, Yaman ;
Danumah, Christophe .
JOURNAL OF NANOPARTICLE RESEARCH, 2013, 16 (01)
[4]  
Bras J., 2010, IND CROP PROD, V32, pG27
[5]   The effect of the cellulose-binding domain from Clostridium cellulovorans on the supramolecular structure of cellulose fibers [J].
Ciolacu, Diana ;
Kovac, Janez ;
Kokol, Vanja .
CARBOHYDRATE RESEARCH, 2010, 345 (05) :621-630
[6]   Conformation and dn/dc determination of cellulose in N,N-dimethylacetamide containing lithium chloride [J].
Dupont, AL ;
Harrison, G .
CARBOHYDRATE POLYMERS, 2004, 58 (03) :233-243
[7]   Maximizing the yield of nanocrystalline cellulose from cotton pulp fiber [J].
Fan, Jin-shi ;
Li, Yan-hao .
CARBOHYDRATE POLYMERS, 2012, 88 (04) :1184-1188
[8]   Extraction and characterization of cellulose nanocrystals from agro-industrial residue - Soy hulls [J].
Flauzino Neto, Wilson Pires ;
Silverio, Hudson Alves ;
Dantas, Noelio Oliveira ;
Pasquini, Daniel .
INDUSTRIAL CROPS AND PRODUCTS, 2013, 42 :480-488
[9]   Bacterial cellulose nanocrystals exhibiting high thermal stability and their polymer nanocomposites [J].
George, Johnsy ;
Ramana, K. V. ;
Bawa, A. S. ;
Siddaramaiah .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2011, 48 (01) :50-57
[10]   Highly filled bionanocomposites from functionalized polysaccharide nanocrystals [J].
Habibi, Youssef ;
Dufresne, Alain .
BIOMACROMOLECULES, 2008, 9 (07) :1974-1980