Iron-surfactant nanocomposite-catalyzed benzylic oxidation in water

被引：20

作者：

Szabo, Fruzsina ^{[1
]}

Petho, Balint ^{[1
]}

Gonda, Zsombor ^{[1
]}

Novak, Zoltan ^{[1
]}

机构：

[1] Eotvos Lorand Univ, Inst Chem, H-1117 Budapest, Hungary

来源：

RSC ADVANCES | 2013年 / 3卷 / 15期

关键词：

TERT-BUTYL HYDROPEROXIDE; SATURATED-HYDROCARBONS; ORGANIC-REACTIONS; SELECTIVE OXIDATION; CROSS-COUPLINGS; GIF CHEMISTRY; FUNCTIONALIZATION; ALKANES; KETONES; MECHANISM;

D O I：

10.1039/c3ra22856h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Benzylic oxidation in the presence of an iron-surfactant nanocomposite catalyst under aqueous conditions is described. A significant reaction rate acceleration in the presence of anionic surfactants was demonstrated. Several benzylic substrates were efficiently transformed to ketones under mild conditions.

引用

页码：4903 / 4908

页数：6

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