Reaction from Dimethyl Carbonate (DMC) to Diphenyl Carbonate (DPC). 2. Kinetics of the Reactions from DMC via Methyl Phenyl Carbonate to DPC

被引：31

作者：

Haubrock, J. ^{[1
]}

Wermink, W. ^{[1
]}

Versteeg, G. F. ^{[1
,2
]}

Kooijman, H. A. ^{[2
]}

Taylor, R. ^{[2
]}

Annaland, M. van Sint ^{[1
]}

Hogendoorn, J. A. ^{[1
]}

机构：

[1] Univ Twente, Dept Sci & Technol, NL-7500 AE Enschede, Netherlands

[2] Clarkson Univ, Dept Chem & Biomol Engn, Potsdam, NY 13699 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2008年 / 47卷 / 24期

关键词：

Batch reactors;

D O I：

10.1021/ie071176d

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetics of the reaction of dimethyl carbonate (DMC) and phenol to methyl phenyl carbonate (MPC) and the subsequent disproportion and transesterification reaction of methyl phenyl carbonate (MPC) to dipheryl carbonate (DPC) have been studied. Experiments were carried out in a closed batch reactor in the temperature range from 160 to 200 degrees C for initial reactant ratios of DMC/phenol from 0.25 to 3 and varying catalyst (titanium-(n-butoxide)) concentrations. The concept of a closed, ideally stirred, isothermal batch reactor incorporating an activity based reaction rate model has been used to fit kinetic parameters to the experimental data taking into account the catalyst concentration, the initial reactant ratio DMC/phenol and the temperature.

引用

页码：9862 / 9870

页数：9