Discussion on "Electrochemistry of CO2 corrosion of mild steel: Effect of CO2 on iron dissolution reaction" by A. Kahyarian, B. Brown, S. Nesic, [Corros. Seri. 129 (2017) 146-151]

被引:24
作者
Almeida, T. C. [1 ]
Bandeira, M. C. E. [1 ]
Moreira, R. M. [1 ]
Mattos, O. R. [1 ]
机构
[1] Univ Fed Rio de Janeiro, COPPE, Lab Ensaios Nao Destrut Corrosao & Soldagem LNDC, Cx Postal 685055, BR-21945970 Rio De Janeiro, RJ, Brazil
关键词
CO2; corrosion; Iron dissolution; Mechanism; Polarization; EIS; IMPEDANCE MEASUREMENTS; HYDROGEN EVOLUTION; AQUEOUS-SOLUTIONS; MECHANISM; ELECTRODE; BEHAVIOR; KINETICS; MODEL;
D O I
10.1016/j.corsci.2018.02.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This discussion presents an analysis of the recent paper by Kahyarian, Brown and Nesic published in this Journal Kahyarian et al. (2017). Indeed, the paper claims an anodic participation of CO2 in the iron dissolution mechanism, not detected by our work also published in this same journal Almeida et al. (2017). The anodic role was, however, only limited to the analysis of Tafel slopes behaviour. This is what was typically done in the early works of iron dissolution in acid media during the 1960's, so that a discussion about this methodology based on the progress of the electrochemistry that has been developed since the 1980's is absolutely necessary.
引用
收藏
页码:417 / 422
页数:6
相关论文
共 30 条
[1]   New insights on the role of CO2 in the mechanism of carbon steel corrosion [J].
Almeida, Tatiana das Chagas ;
Elaine Bandeira, Merlin Cristina ;
Moreira, Rogaciano Maia ;
Mattos, Oscar Rosa .
CORROSION SCIENCE, 2017, 120 :239-250
[2]   A new experimental approach to the time-constants of electrochemical impedance:: frequency response of the double layer capacitance [J].
Antaño-Lopez, R ;
Keddam, M ;
Takenouti, H .
ELECTROCHIMICA ACTA, 2001, 46 (24-25) :3611-3617
[3]   THE ANODIC BEHAVIOR OF IRON IN ETHANOL WATER SOLUTIONS IN THE PRESENCE AND ABSENCE OF NACLO4 AS THE SUPPORTING ELECTROLYTE [J].
ATHAYDE, MG ;
MATTOS, OR ;
SATHLER, L .
ELECTROCHIMICA ACTA, 1987, 32 (06) :909-913
[4]   THE ROLE OF CHLORIDE AND SULFATE ANIONS IN THE IRON DISSOLUTION MECHANISM STUDIED BY IMPEDANCE MEASUREMENTS [J].
BARCIA, OE ;
MATTOS, OR .
ELECTROCHIMICA ACTA, 1990, 35 (06) :1003-1009
[5]  
BECHET B, 1977, J ELECTROANAL CHEM, V76, P129, DOI 10.1016/0368-1874(77)80079-8
[6]   KINETICS OF IRON DISSOLUTION AND PASSIVATION [J].
BESSONE, J ;
KARAKAYA, L ;
LORBEER, P ;
LORENZ, WJ .
ELECTROCHIMICA ACTA, 1977, 22 (10) :1147-1154
[7]  
Bockris J.O., 1962, ELECTROCHIM ACTA, V7, P293, DOI DOI 10.1016/0013-4686(62)87007-8
[8]  
Bockris J.O.M., 1961, ELECTROCHIM ACTA, V4, P325, DOI [10.1016/0013-4686(61)80026-1, DOI 10.1016/0013-4686(61)80026-1]
[9]  
BONHOEFFER KF, 1951, Z ELEKTROCHEM, V55, P151
[10]  
Cid M., J ELECTROCHEM SOC, V128