Kinetics and mechanism of the oxidation of [Fe(CN)6]4- to [Fe(CN)6]3-, induced by the reaction between Cu2+ and I- in aqueous solution.: Oxidation reaction by a radical anion I2-•

被引：13
|
作者：
Kimura, M [1 ]
Shiota, Y [1 ]
Kishi, S [1 ]
Tsukahara, K [1 ]
机构：
[1] Nara Womens Univ, Fac Sci, Dept Chem, Nara 6308506, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1999年 / 72卷 / 06期
关键词：
D O I：
10.1246/bcsj.72.1293
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hexacyanoferrate(II) ion ([Fe(CN)(6)](4-)) was rapidly oxidized to [Fe(CN)(6)](3-) by a radical anion, I-2(-.), which was formed by a reaction between the copper(II) ion and the iodide ion. The oxidation reaction was accelerated by increasing the pH. Under the conditions of lower pH's, the [Fe(CN)(6)](3-) acted as a retarder to the oxidation reaction. The mechanisms for such reactions are discussed in terms of accounting for the obtained results.
引用
收藏
页码：1293 / 1299
页数：7
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