Kinetics and mechanism of the oxidation of [Fe(CN)6]4- to [Fe(CN)6]3-, induced by the reaction between Cu2+ and I- in aqueous solution.: Oxidation reaction by a radical anion I2-•

被引：13

作者：

Kimura, M ^{[1
]}

Shiota, Y ^{[1
]}

Kishi, S ^{[1
]}

Tsukahara, K ^{[1
]}

机构：

[1] Nara Womens Univ, Fac Sci, Dept Chem, Nara 6308506, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1999年 / 72卷 / 06期

关键词：

D O I：

10.1246/bcsj.72.1293

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hexacyanoferrate(II) ion ([Fe(CN)(6)](4-)) was rapidly oxidized to [Fe(CN)(6)](3-) by a radical anion, I-2(-.), which was formed by a reaction between the copper(II) ion and the iodide ion. The oxidation reaction was accelerated by increasing the pH. Under the conditions of lower pH's, the [Fe(CN)(6)](3-) acted as a retarder to the oxidation reaction. The mechanisms for such reactions are discussed in terms of accounting for the obtained results.

引用

页码：1293 / 1299

页数：7

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