[Sc2(μ-OH)2(H2O)6(NO3)2](NO3)2: Aqueous Synthesis and Characterization

被引：12

作者：

Wang, Wei ^{[1
]}

Chang, I-Ya ^{[1
]}

Zakharov, Lev ^{[1
]}

Cheong, Paul Ha-Yeon ^{[1
]}

Keszler, Douglas A. ^{[1
]}

机构：

[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 04期

基金：

美国国家科学基金会;

关键词：

SCANDIUM OXIDE; WATER;

D O I：

10.1021/ic301814z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Sc-2(mu-OH)(2)(H2O)(6)(NO3)(2)](NO3)(2) has been synthesized from an aqueous scandium nitrate solution by using zinc powder as a reducing agent for nitric acid, which drives an increase in pH and forces the condensation of aqua scandium cations. This preparative route readily produces gram-scale samples with yields near 65%. A single-crystal X-ray diffraction study reveals a structure characterized by a hydroxo-bridged Sc dimer. The FTIR spectrum of the compound has been modeled via ab initio computations, allowing the identification of signature IR peaks. Some initial observations on the thermal transformation of the compound to Sc2O3 are also reported.

引用

收藏

页码：1807 / 1811

页数：5

相关论文

共 50 条

[21] New type of [Bi6O6(OH)3](NO3)3•1.5H2O sheets photocatalyst with high photocatalytic activity on degradation of phenol [J].

Yang, Yuxiao ;

Liang, Huoyan ;

Zhu, Na ;

Zhao, Yaping ;

Guo, Changsheng ;

Liu, Lu .

CHEMOSPHERE, 2013, 93 (04) :701-707

[22] Reaction Chemistry during the Atomic Layer Deposition of Sc2O3 and Gd2O3 from Sc(MeCp)3, Gd(iPrCp)3, and H2O [J].

Han, Jeong Hwan ;

Nyns, Laura ;

Delabie, Annelies ;

Franquet, Alexis ;

Van Elshocht, Sven ;

Adelmann, Christoph .

CHEMISTRY OF MATERIALS, 2014, 26 (03) :1404-1412

[23] An in situ annealing route to [Bi6O6(OH)2](NO3)4•2H2O/g-C3N4 heterojunction and its visible-light-driven photocatalytic performance [J].

Ma, Yuanyuan ;

Han, Qiaofeng ;

Wang, Xin ;

Zhu, Junwu .

MATERIALS RESEARCH BULLETIN, 2018, 101 :272-279

[24] Chemical and thermal destruction of the platinum blue {Pt(Bipy)(NHCOCH3)2NO3 • mH2O}. The molecular and crystal structures of new binuclear Pt(III) acetamide [Pt2(Bipy)2(NHCOCH3)2(μ-NHCOCH3)2](NO3)2 • H2O [J].

Fedotova, T. N. ;

Aleksandrov, G. G. ;

Dobrokhotova, Zh. V. ;

Kuznetsova, G. N. ;

Eremenko, I. L. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (07) :777-782

[25] Study on Vapor-Liquid Equilibrium and Microscopic Properties of Glycine + H2O, <sc>l</sc>-Histidine + H2O, and <sc>l</sc>-Tryptophan + H2O [J].

Li, Xia ;

Liu, Weiping ;

Yin, Yahui ;

Zhou, Yu ;

Xiang, Hongfei ;

Xu, Xianzhen .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2023, 68 (12) :3306-3315

[26] A COMPARATIVE INVESTIGATION OF Al2O3/H2O, SiO2/H2O AND ZrO2/H2O NANOFLUID FOR HEAT TRANSFER APPLICATIONS [J].

Iqbal, S. M. ;

Raj, C. S. ;

Michael, J. J. ;

Irfan, A. M. .

DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 2017, 12 (02) :255-263

[27] Magnetic Fe3O4/Bi2O2(OH)(NO3) as a sunlight-driven photocatalyst for rhodamine B degradation [J].

Dulyasucharit, Ruethaithip ;

Wongkasemjit, Sujitra ;

Nanan, Suwat ;

Intharaksa, Orapan ;

Masingboon, Chivalrat .

JOURNAL OF SOLID STATE CHEMISTRY, 2023, 319

[28] Zn3V2O7(OH)2(H2O)2 and Zn3V2O8 nanostructures: controlled fabrication and photocatalytic performance [J].

Shi, Rui ;

Wang, Yajun ;

Zhou, Feng ;

Zhu, Yongfa .

JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (17) :6313-6320

[29] SystEme quasi ternaire H2O-Zn(NO3)2·6H2O-NH4NO3 II. les Isothermes 0; 15 et 20°C [J].

A. Ibnlfassi ;

M. Kaddami .

Journal of Thermal Analysis and Calorimetry, 2004, 76 :775-782

[30] Phase Equilibria and Thermodynamic Properties of Phases in the H2O-Gd(NO3)3 System [J].

Dzuban, A. V. ;

Novikov, A. A. ;

Nesterov, A. V. ;

Qianchen, Sh. ;

Kovalenko, N. A. ;

Uspenskaya, I. A. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2022, 67 (SUPPL 2) :S177-S183

← 1 2 3 4 5 →