Recent developments in the coordination chemistry of bis(imino)acenaphthene (BIAN) ligands with s- and p-block elements

被引：139

作者：

Hill, Nicholas J. ^{[2
]}

Vargas-Baca, Ignacio

Cowley, Alan H. ^{[1
]}

机构：

[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA

[2] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

DALTON TRANSACTIONS | 2009年 / 02期

基金：

加拿大自然科学与工程研究理事会; 美国国家科学基金会;

关键词：

TRANSITION-METAL-COMPLEXES; AMIDO-IMINO LIGAND; MOLECULAR-STRUCTURES; CRYSTAL-STRUCTURES; CALCIUM COMPLEXES; SINGLE-ELECTRON; IPR-DAB; STRUCTURAL-CHARACTERIZATION; LIVING POLYMERIZATION; COPPER(II) COMPLEXES;

D O I：

10.1039/b815079f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(imino)acenaphthenes (BIAN) have been known for many years. However, it is only since the 1990s that such compounds have been recognized as robust ligands for the support of catalytically active transition metal centers. More recently, the unique stereoelectronic properties of the BIAN ligand class are beginning to be appreciated and exploited for some fascinating new developments in synthetic, structural and catalytic s- and p-block chemistry.

引用

页码：240 / 253

页数：14

共 139 条

[1] Photochemical bond homolysis in a novel series of metal-metal bonded complexes Ru(E)(E')(CO)(2)(iPr-DAB) [J].

Aarnts, MP ;

Stufkens, DJ ;

Vlcek, A .

INORGANICA CHIMICA ACTA, 1997, 266 (01) :37-46

[2] Bonding properties of a novel inorganometallic complex, Ru(SnPh(3))(2)(CO)(2)(iPr-DAB) (iPr-DAB=N,N'-diisopropyl-1,4-diaza-1,3-butadiene), and its stable radical-anion, studied by UV-Vis, IR, and EPR spectroscopy, (spectro-) electrochemistry, and density functional calculations [J].

Aarnts, MP ;

Wilms, MP ;

Peelen, K ;

Fraanje, J ;

Goubitz, K ;

Hartl, F ;

Stufkens, DJ ;

Baerends, EJ ;

Vlcek, A .

INORGANIC CHEMISTRY, 1996, 35 (19) :5468-5477

[3] Spectroelectrochemical (UV-Vis, IR, NMR, and EPR) study of the inorganometallic complexes Ru(E)(E')(CO)(2)(iPr-DAB) (E = Cl, E' = SnPh3, PbPh3; E = Me, SnPh3, GePh3, E' = SnPh3; E = E' = PbPh3; iPr-DAB = 1,4-diisopropyl-1,4-diaza-1,3-butadiene) [J].

Aarnts, MP ;

Hartl, F ;

Peelen, K ;

Stufkens, DJ ;

Amatore, C ;

Verpeaux, JN .

ORGANOMETALLICS, 1997, 16 (21) :4686-4695

[4] Near-infrared luminescence from platinum(II) diimine compounds [J].

Adams, Christopher J. ;

Fey, Natalie ;

Weinstein, Julia A. .

INORGANIC CHEMISTRY, 2006, 45 (16) :6105-6107

[5] Bis(amido)magnesium mediated aldol additions: first structural characterisation of an amidomagnesium aldolate intermediate [J].

Allan, JF ;

Henderson, KW ;

Kennedy, AR .

CHEMICAL COMMUNICATIONS, 1999, (14) :1325-1326

[6] Synthesis and structural characterisation of a magnesium bisenolate:: a tetrameric (Mg2O2)2 chain terminated by solvating ketone [J].

Allan, JF ;

Henderson, KW ;

Kennedy, AR ;

Teat, SJ .

CHEMICAL COMMUNICATIONS, 2000, (12) :1059-1060

[7] Imidazolylidenes, imidazolinylidenes and imidazolidines [J].

Arduengo, AJ ;

Krafczyk, R ;

Schmutzler, R ;

Craig, HA ;

Goerlich, JR ;

Marshall, WJ ;

Unverzagt, M .

TETRAHEDRON, 1999, 55 (51) :14523-14534

[8] Synthesis, X-ray crystal structure and solution NMR spectroscopic studies of [Li{N(H)C(Me)=C(H)(CN)}(py)(2)](2) (py=NC5H5) [J].

Avent, AG ;

Frankland, AD ;

Hitchcock, PB ;

Lappert, MF .

CHEMICAL COMMUNICATIONS, 1996, (21) :2433-2434

[9]

Bailey PJ, 2006, DALTON T, P1602, DOI 10.1039/b514591k

[10] Structural and EPR characterisation of single electron and alkyl transfer products from reaction of dimethyl magnesium with bulky α-diimine ligands [J].

Bailey, PJ ;

Coxall, RA ;

Dick, CM ;

Fabre, S ;

Parsons, S ;

Yellowlees, LJ .

CHEMICAL COMMUNICATIONS, 2005, (36) :4563-4565

← 1 2 3 4 5 6 7 8 9 10 →