Formation of TiO2-xFx compounds in fluorine-implanted TiO2

被引:110
作者
Yamaki, T [1 ]
Sumita, T [1 ]
Yamamoto, S [1 ]
机构
[1] Japan Atom Energy Res Inst, Takasaki Radiat Chem Res Estab, Dept Mat Dev, Gunma 3701292, Japan
关键词
D O I
10.1023/A:1014282225859
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
F ions were implanted in TiO2 rutile single crystals. The effects of subsequent thermal annealing were investigated by Rutherford backscattering and channeling (RBS-C) studies, X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy (SIMS). Optically polished single-crystalline TiO2 with a crystallographic axis was used for the analysis. The method enabled dopants to be introduced in a controlled manner at specific locations to realize impurity concentration gradients in TiO2.
引用
收藏
页码:33 / 35
页数:3
相关论文
共 13 条
[1]  
[Anonymous], METALLURGICAL THERMO
[2]   Design of unique titanium oxide photocatalysts by an advanced metal ion-implantation method and photocatalytic reactions under visible light irradiation [J].
Anpo, M ;
Ichihashi, Y ;
Takeuchi, M ;
Yamashita, H .
RESEARCH ON CHEMICAL INTERMEDIATES, 1998, 24 (02) :143-149
[3]   ELECTROCHROMISM IN TUNGSTEN OXYFLUORIDE FILMS MADE BY CHEMICALLY ENHANCED DC SPUTTERING [J].
AZENS, A ;
STJERNA, B ;
GRANQVIST, CG ;
GABRUSENOKS, J ;
LUSIS, A .
APPLIED PHYSICS LETTERS, 1994, 65 (16) :1998-2000
[4]  
DARKEN LS, 1953, PHYSICAL CHEM METALS
[5]   HETEROGENEOUS PHOTOCATALYSIS [J].
FOX, MA ;
DULAY, MT .
CHEMICAL REVIEWS, 1993, 93 (01) :341-357
[6]   Ion implantation in TiO2:: damage production and recovery, lattice site location and electrical conductivity [J].
Fromknecht, R ;
Khubeis, I ;
Massing, S ;
Meyer, O .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1999, 147 (1-4) :191-201
[7]   EFFECTS OF IMPLANTATION IN RUTILE WITH METALLIC-IONS [J].
GUERMAZI, M ;
THEVENARD, P ;
DUPIN, JP ;
DUPUY, CHS .
RADIATION EFFECTS AND DEFECTS IN SOLIDS, 1980, 49 (1-3) :61-64
[8]   EVIDENCE OF NEW PHASE CREATION IN IMPLANTED TIO2 [J].
GUERMAZI, M ;
THEVENARD, P ;
DUPIN, JP ;
DUPUY, CHS .
NUCLEAR INSTRUMENTS & METHODS, 1981, 182 (APR) :397-406
[9]   A promoting effect of NH4F addition on the photocatalytic activity of sol-gel TiO2 films [J].
Hattori, A ;
Yamamoto, M ;
Tada, H ;
Ito, S .
CHEMISTRY LETTERS, 1998, (08) :707-708
[10]  
Meyer O., 1987, Material Science Reports, V2, P371, DOI 10.1016/0920-2307(87)90003-X