Synthesis and characterization of a polymer-supported heteropolytungstate catalyst for oxidation of benzyl alcohol

被引：18

作者：

Weng, Zhihuan ^{[1
]}

Wang, Jinyan ^{[1
]}

Zhang, Shouhai ^{[1
]}

Yan, Chun ^{[1
]}

Jian, Xigao ^{[1
]}

机构：

[1] Dalian Univ Technol, Liaoning Res Ctr High Performance Resin Engn & Te, Dept Polymer Sci & Mat, Dalian 116012, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 10卷 / 02期

基金：

国家高技术研究发展计划(863计划);

关键词：

Heteropolytungstate; Poly(phthalazinone ether sulfone ketone); Polymer-supported; Benzyl alcohol; Hydrogen peroxide;

D O I：

10.1016/j.catcom.2008.03.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A polymer poly(phthalazinone ether sulfone ketone) (PPESK) was employed as support to load heteropoly anion [PW9O34](9-) with chemical interaction. The organic-inorganic hybrid material was characterized by FT-IR and TGA. In liquid-phase oxidation of benzyl alcohol to benzaldehyde with hydrogen peroxide as oxidant, the supported catalyst exhibited high catalytic activity under mild reaction conditions. Leaching and recycling experiments confirmed that the heteropoly anions immobilized on polymer matrix were stable. (C) 2008 Published by Elsevier B.V.

引用

页码：125 / 128

页数：4

共 50 条

[1] Direct conversion of benzyl alcohol to ketone by polymer-supported Rh catalyst
Jun, CH
Hong, HS
Huh, CW
TETRAHEDRON LETTERS, 1999, 40 (50) : 8897 - 8900
[2] ANODIC-OXIDATION OF BENZYL ALCOHOL TO BENZALDEHYDE IN THE PRESENCE OF BOTH REDOX MEDIATOR AND POLYMER-SUPPORTED PHASE-TRANSFER CATALYST
DO, JS
CHOU, TC
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1992, 22 (10) : 966 - 972
[3] Synthesis, Characterization and Use of Polymer-Supported Phase Transfer Catalyst in Organic Reactions
Kaur, Inderjeet
Kumari, Vandna
Dhiman, Poonam K.
JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 121 (06) : 3185 - 3191
[4] Selectivity engineering with polymer-supported reagents: oxidation of benzyl chloride to benzaldehyde
Yadav, G.D.
Haldavanekar, B.V.
(32):
[5] Selectivity engineering with polymer-supported reagents: Oxidation of benzyl chloride to benzaldehyde
Yadav, GD
Haldavanekar, BV
REACTIVE & FUNCTIONAL POLYMERS, 1997, 32 (02): : 187 - 194
[6] CHARACTERIZATION OF THE POLYMER-SUPPORTED PHASE-TRANSFER CATALYST
CHOU, SC
WENG, HS
JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 39 (08) : 1665 - 1679
[7] Selectivity engineering with polymer-supported reagents: oxidation of benzyl chloride to benzaldehyde
Yadav, G.D.
Haldavanekar, B.V.
(32):
[8] Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst
Zhi Huan Weng Jin Yan Wang Xi Gao Jian~* Department of Polymer Science and Materials
ChineseChemicalLetters, 2007, (08) : 936 - 938
[9] Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst
Weng, Zhi Huan
Wang, Jin Yan
Jian, Xi Gao
CHINESE CHEMICAL LETTERS, 2007, 18 (08) : 936 - 938
[10] A polymer-supported scandium catalyst
Kobayashi, S
Nagayama, S
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (07): : 2256 - 2257

← 1 2 3 4 5 →