Ultrasound-assisted fabrication of a novel nickel(II)-bis-pyrazolyl borate two-nuclear discrete nano-structured coordination compound

被引：27

作者：

Hanifehpour, Younes ^{[1
]}

Morsali, Ali ^{[2
]}

Soltani, Behzad ^{[3
]}

Mirtamizdoust, Babak ^{[4
]}

Joo, Sang Woo ^{[1
]}

机构：

[1] Yeungnam Univ, Sch Mech Engn, Kyongsan 712749, South Korea

[2] Tarbiat Modares Univ, Dept Chem, Fac Sci, POB 14115-4838, Tehran, Iran

[3] Azarbaijan Shahid Madani Univ, Dept Chem, Fac Basic Sci, Tabriz, Iran

[4] Univ Qom, Fac Sci, Dept Chem, POB 37185-359, Qom, Iran

来源：

ULTRASONICS SONOCHEMISTRY | 2017年 / 34卷

基金：

新加坡国家研究基金会;

关键词：

Nickel; Pyrazolyl borate; Nano coordination compounds; DFT calculations; Sonochemical; METAL-ORGANIC FRAMEWORK; SONOCHEMICAL SYNTHESES; CRYSTAL-STRUCTURE; DFT CALCULATIONS; LEAD(II) OXIDE; COMPLEXES; CHEMISTRY; PRECURSOR; POLYMER; DESIGN;

D O I：

10.1016/j.ultsonch.2016.06.032

中图分类号：

O42 [声学];

学科分类号：

070206 ; 082403 ;

摘要：

Ultrasound was used to synthesize nano-structures of [Ni(bpzB)(2)](2)(1), a new two-nuclear discrete coordination compound of divalent nickel with bis-pyrazolyl borate(bpzB). The nanostructure was characterized by scanning electron microscopy, X-ray powder diffraction, infrared, and elemental analysis. The single-crystal X-ray data show that the coordination number of Ni(II) ions is four (Ni1N(4) and Ni2N(4)) with square planar geometry. The supramolecular features in these complexes are guided and controlled by weak directional intermolecular interactions. The discrete molecules interact with each other through labile interactions, creating a 3D supramolecular framework. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：519 / 524

页数：6

共 45 条

[1] Synthesis, structural characterization, magnetic behavior, and single crystal EPR spectra of three new one-dimensional manganese azido systems with FM, alternating FM-AF, and AF coupling [J].