Dynamic and structural evaluation of poly(3-hydroxybutyrate) layered nanocomposites

被引：14

作者：

Rocha e Silva, Mariana Bruno ^{[1
]}

Bruno Tavares, Maria Ines ^{[1
]}

da Silva, Emerson Oliveira ^{[1
]}

Cucinelli Neto, Roberto Pinto ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, Inst Macromol Prof Eloisa Mano, Ctr Tecnol, Ilha Fundao, BR-21941598 Rio De Janeiro, RJ, Brazil

来源：

POLYMER TESTING | 2013年 / 32卷 / 01期

关键词：

PHB; LF-NMR; Nanocomposite; NYLON-6 CLAY NANOCOMPOSITES; SPECTROSCOPY; CRYSTALLIZATION; FILMS;

D O I：

10.1016/j.polymertesting.2012.09.006

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Layered poly(3-hydroxybutyrate) (PHB) nanostructured materials were prepared containing two commercial organophilic clays, Viscogel B8 and Viscogel S7, at clay concentrations of 1%, 3%, 5%, 7% and 10%. The materials obtained were characterized by the traditional methods of X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry and optical microscopy, as well as an alternative method, low-field nuclear magnetic resonance. The nanostructured materials obtained presented an excellent degree of intercalation/exfoliation and the clay was able to promote changes in the polymer's structure, reducing its crystallinity degree. (c) 2012 Elsevier Ltd. All rights reserved.

引用

页码：165 / 174

页数：10

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