New Perspectives on Polyoxometalate Catalysts: Alcohol Oxidation with Zn/Sb-Polyoxotungstates

被引：47

作者：

Ni, Lubin ^{[2
]}

Patscheider, Joerg ^{[3
]}

Baldridge, Kim K. ^{[1
]}

Patzke, Greta R. ^{[2
]}

机构：

[1] Univ Zurich, Inst Organ Chem, CH-8057 Zurich, Switzerland

[2] Univ Zurich, Inst Inorgan Chem, CH-8057 Zurich, Switzerland

[3] EMPA Dubendorf, Lab Nanoscale Mat Sci, CH-8600 Dubendorf, Switzerland

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 42期

基金：

瑞士国家科学基金会;

关键词：

alcohol oxidation; antimony; computational methods; homogeneous catalysis; polyoxometalates; HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; EPOXIDATION; OXYGEN; WATER; ISOMERIZATION; ANTIMONY; METAL; HETEROPOLYANIONS; CHEMISTRY;

D O I：

10.1002/chem.201202924

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic belts are the crucial feature of Zn/Sb-polyoxometalates as efficient and selective catalysts for alcohol oxidation. Comprehensive theoretical, analytical, and catalytic studies identify the active role of the Sb atom in the polyoxometalate metal belt. This sheds new light on low-cost catalyst tuning strategies for crucial oxidative transformations. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13293 / 13298

页数：6

共 55 条

[31] Electronic properties of polyoxometalates:: A DFT study of α/β-[XM12O40]n- relative stability (M = W, Mo and X a main group element) [J].

López, X ;

Maestre, JM ;

Bo, C ;

Poblet, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (39) :9571-9576

[32] Current trends in the computational modelling of polyoxometalates [J].

Lopez, Xavier ;

Miro, Pere ;

Carbo, Jorge J. ;

Rodriguez-Fortea, Antonio ;

Bo, Carles ;

Poblet, Josep M. .

THEORETICAL CHEMISTRY ACCOUNTS, 2011, 128 (4-6) :393-404

[33] Oxidation of alcohols with molecular oxygen on solid catalysts [J].

Mallat, T ;

Baiker, A .

CHEMICAL REVIEWS, 2004, 104 (06) :3037-3058

[34] Recent advances in immobilized metal catalysts for environmentally benign oxidation of alcohols [J].

Matsumoto, Tsutomu ;

Ueno, Masaharu ;

Wang, Naiwei ;

Kobayashi, Shu .

CHEMISTRY-AN ASIAN JOURNAL, 2008, 3 (02) :196-214

[35] Assembly of titanium embedded polyoxometalates with unprecedented structural features [J].

McGlone, Thomas ;

Vila-Nadal, Laia ;

Miras, Haralampos N. ;

Long, De-Liang ;

Poblet, Josep M. ;

Cronin, Leroy .

DALTON TRANSACTIONS, 2010, 39 (48) :11599-11604

[36] Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates [J].

Mizuno, N ;

Yamaguchi, K ;

Kamata, K .

COORDINATION CHEMISTRY REVIEWS, 2005, 249 (17-18) :1944-1956

[37] Reinvestigation of a Ru2-Incorporated Polyoxometalate Dioxygenase Precatalyst, "[WZnRu2III(H2O)(OH)(ZnW9O34)2]11-": Evidence For Marginal, ≤0.2 Equivalents of Ru Incorporation Plus Faster Catalysis by Physical Mixtures of [RuII(DMSO)4Cl2] and the Parent Polyoxometalate [WZn3(H2O)2(ZnW9O34)2]12- [J].

Morris, Aimee M. ;

Anderson, Oren P. ;

Finke, Richard G. .

INORGANIC CHEMISTRY, 2009, 48 (10) :4411-4420

[38] A new dinuclear rhodium(III) 'sandwich' polyoxometalate, [(WZnRH(2)(III))(ZnW9O34)(2)](10-). Synthesis, characterization and catalytic activity [J].

Neumann, R ;

Khenkin, AM .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 114 (1-3) :169-180

[39] THE MANGANESE-CONTAINING POLYOXOMETALATE, [WZNMN2II(ZNW9O34)(2)](12-), AS A REMARKABLY EFFECTIVE CATALYST FOR HYDROGEN-PEROXIDE MEDIATED OXIDATIONS [J].

NEUMANN, R ;

GARA, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (18) :5066-5074

[40]

Okuhara T, 1996, ADV CATAL, V41, P113, DOI 10.1016/S0360-0564(08)60041-3

← 1 2 3 4 5 6 →