New Perspectives on Polyoxometalate Catalysts: Alcohol Oxidation with Zn/Sb-Polyoxotungstates

被引：47

作者：

Ni, Lubin ^{[2
]}

Patscheider, Joerg ^{[3
]}

Baldridge, Kim K. ^{[1
]}

Patzke, Greta R. ^{[2
]}

机构：

[1] Univ Zurich, Inst Organ Chem, CH-8057 Zurich, Switzerland

[2] Univ Zurich, Inst Inorgan Chem, CH-8057 Zurich, Switzerland

[3] EMPA Dubendorf, Lab Nanoscale Mat Sci, CH-8600 Dubendorf, Switzerland

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 42期

基金：

瑞士国家科学基金会;

关键词：

alcohol oxidation; antimony; computational methods; homogeneous catalysis; polyoxometalates; HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; EPOXIDATION; OXYGEN; WATER; ISOMERIZATION; ANTIMONY; METAL; HETEROPOLYANIONS; CHEMISTRY;

D O I：

10.1002/chem.201202924

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic belts are the crucial feature of Zn/Sb-polyoxometalates as efficient and selective catalysts for alcohol oxidation. Comprehensive theoretical, analytical, and catalytic studies identify the active role of the Sb atom in the polyoxometalate metal belt. This sheds new light on low-cost catalyst tuning strategies for crucial oxidative transformations. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13293 / 13298

页数：6

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