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Aniline-terephthalaldehyde resin p-toluenesulfonate (ATRT) as a highly efficient and reusable catalyst for alcoholysis, hydrolysis, and acetolysis of epoxides
被引:1
|作者:
Tanemura, Kiyoshi
[1
]
Suzuki, Tsuneo
[1
]
机构:
[1] Nippon Dent Univ, Chem Lab, Sch Life Dent, Hamaura Cho, Niigata 9518580, Japan
关键词:
Acetolysis;
alcoholysis;
aniline resins;
epoxides;
hydrolysis;
solid acids;
DICYANOKETENE ACETALS;
AMMONIUM-NITRATE;
ACID CATALYST;
SILYL ETHERS;
ACETIC-ACID;
MILD;
TETRAHYDROPYRANYLATION;
TETRACYANOETHYLENE;
WATER;
PROTECTION;
D O I:
10.1080/00397911.2016.1223309
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Alcoholysis, hydrolysis, and acetolysis of epoxides were carried out in the presence of a catalytic amount of aniline-terephthalaldehyde resin p-toluenesulfonate (ATRT) to give the corresponding -substituted alcohols in good yields. Alcoholysis and hydrolysis of epoxides catalyzed by ATRT proceeded faster than those by pyridinium p-toluenesulfonate (PPTS). [GRAPHICS]
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页码:1781 / 1789
页数:9
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