Co-Zeolite Imidazolate Frameworks (ZIF-9@Zeolite) as Heterogen Catalyst for Alcohols Oxidation

被引：19

作者：

Hashemian, Saeedeh ^{[1
]}

Sedrpoushan, Alireza ^{[2
]}

Eshbala, Fereshteh Hosseini ^{[2
]}

机构：

[1] Islamic Azad Univ, Yazd Brunch, Dept Chem, Yazd, Iran

[2] Iranian Res Org Sci & Technol, Inst Ind Chem, Tehran, Iran

来源：

CATALYSIS LETTERS | 2017年 / 147卷 / 01期

关键词：

Alcohol; Aldehyde; Heterogen catalysis; Oxidation; Zeolitic imidazolate frameworks (ZIFs); SELECTIVE OXIDATION; CARBOXYLIC-ACIDS; BENZYL ALCOHOL; NANOPARTICLES; HYDROGENATION; ADSORPTION; CONVERSION; ZIF-67; AIR;

D O I：

10.1007/s10562-016-1855-x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cobalt zeolitic imidazolate framework (ZIF-9@Zeolite) was synthesized by Co(II) nitrate, benzylimidazole and zeolite. It was characterized by the FTIR, SEM, TEM and BET methods. Efficient catalytic oxidation of benzyl alcohols into corresponding benzaldehydes was studied using catalytic system of ZIF-9@Zeolite. The effect of different factors such as the amount of oxidant, reaction time and reaction temperature on the oxidation reaction was investigated. Interestingly, ZIF-9@Zeolite was very efficient for the oxidation reaction of alcohols and a high yield of aldehydes could be obtained. [GRAPHICS]

引用

页码：196 / 203

页数：8

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