The effect of vinyl-containing ionic liquid on the photocatalytic activity of iron-doped TiO2

被引：22

作者：

Deng, Fang ^{[1
,2
]}

Luo, Xubiao ^{[1
,2
]}

Li, Ke ^{[1
,2
]}

Tu, Xinman ^{[1
,2
]}

Luo, Shenglian ^{[1
,2
]}

Yang, Lixia ^{[1
,2
]}

Zhou, Ninghui ^{[1
,2
]}

Shu, Hongying ^{[1
,2
]}

机构：

[1] Key Lab Jiangxi Prov Ecol Diag Remediat & Pollut, Nanchang 330063, Peoples R China

[2] Nanchang Hangkong Univ, Coll Environm & Chem Engn, Nanchang 330063, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2013年 / 366卷

关键词：

Iron-doped TiO2; Ionic liquid; Photocatalytic degradation; 2-Nitrophenol; CEO2-TIO2; NANOPARTICLES; ASSISTED SYNTHESIS; DEGRADATION; NANOCOMPOSITE; FILM; UV;

D O I：

10.1016/j.molcata.2012.09.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Visible light responsive iron-doped TiO2 (Fe3+/TiO2-IL) was synthesized by sol-gel method using 1-vinyl-3-propylimidazolium iodide (VPIM+I-) as a reaction medium. VPIM+I- not only made the morphological and structural changes of Fe3+/TiO2-IL, but also extended its absorption edge to the visible light region. The photocatalytic activity of Fe3+/TiO2-IL was tested in the degradation of 2-nitrophenol under simulated solar light irradiation. The photocatalytic activity of Fe3+/TiO2-IL was higher than the samples prepared in the reaction medium without VPIM+I-. Moreover, the effect of pH and H2O2 on the photocatalytic activity of Fe3+/TiO2-IL was also investigated. Fe3+/TiO2-IL showed high photocatalytic activity in acidic environment, and H2O2 had a dual effect on the photocatalytic activity Fe3+/TiO2-IL. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：222 / 227

页数：6

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