NMR and IR spectra-structure correlations for carbonyl containing compounds in various solvents

被引：28
|
作者：
Nyquist, RA
Streck, R
Jeschek, G
机构：
[1] DOW DEUTSCHLAND INC,ANALYT DEPT,WERK RHEINMUNSTER,D-77836 RHEINMUNSTER,GERMANY
[2] DOW CHEM CO USA,SCI ANALYT LAB,MIDLAND,MI 48667
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1996年 / 377卷 / 02期
关键词：
IR spectroscopy; NMR spectroscopy; spectra-structure correlation; carbonyl compounds;
D O I：
10.1016/0022-2860(95)09120-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The delta(13)C=O chemical shifts and the carbonyl stretching frequencies nu(C=O) are affected by their physical surroundings, and information about the chemical structure can be obtained by study of delta(13)C=O and nu(C=O) in various solvents or solvent systems, Solvent acceptor numbers (AN) are not a precise indicator of delta(13)C=O chemical shifts or nu(C=O) frequencies due to steric factors of both the solute and solvent, which alters the distance between the sites of solute and solvent interaction when the same solvent is used for different solutes of a homologous series.
引用
收藏
页码：113 / 128
页数：16
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