Effective diffusivity through arrays of obstacles under zero-mean periodic driving forces

被引:0
作者
Alvarez-Ramirez, J. [1 ]
Dagdug, L. [1 ]
Valdes-Parada, F. J. [1 ]
机构
[1] Univ Autonoma Metropolitana Iztapalapa, Div Ciencias Basicas & Ingn, Mexico City 09340, DF, Mexico
关键词
Brownian motion; diffusion; stochastic processes; CATALYSIS; TRANSPORT; CHANNELS; IONS;
D O I
10.1063/1.4758703
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We perform a numerical investigation of the transport of Brownian particles driven by a zero-mean periodic force across two-dimensional arrays of obstacles with finite length. By applying axial and transversal driving forces relative to the diffusion transport direction, the effective diffusivity is determined as function of the array geometry and the driving frequency, finding excess diffusion peaks at certain frequency ranges. The results indicate that a suitable selection of the axial and transversal frequencies yields enhanced diffusion transport along the axial direction. Symmetric and asymmetric arrays are considered, showing that the asymmetry has a detrimental effect in the magnitude of the excess diffusion peaks. This suggests that enhanced diffusion is obtained because the oscillatory driving force exploits preferential transport channels, whose effective obstacle spacing is maximized under symmetric configurations. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4758703]
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页数:7
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