Liquid chromatography mass spectrometry and liquid chromatography/nuclear magnetic resonance as complementary analytical techniques for unambiguous identification of polymethoxylated flavones in residues from molecular distillation of orange peel oils (Citrus sinensis)

被引：42
|
作者：
Weber, B [1 ]
Hartmann, B [1 ]
Stöckigt, D [1 ]
Schreiber, K [1 ]
Roloff, M [1 ]
Bertram, HJ [1 ]
Schmidt, CO [1 ]
机构：
[1] Symrise GmbH & Co KG, Corp Res Div, D-37601 Holzminden, Germany
来源：
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 2006年 / 54卷 / 02期
关键词：
LC/NMR; LC/MS; Citrus sinensis; polymethoxylated flavones; polymethoxyflavones; tetranortriterpene; limonoid; proceranone;
D O I：
10.1021/jf051606f
中图分类号：
S [农业科学];
学科分类号：
09 ;
摘要：
Liquid chromatography/mass spectrometry and liquid chromatography/nuclear magnetic resonance techniques with ultraviolet/diode array detection were used as complementary analytical tools for the reliable identification of polymethoxylated flavones in residues from molecular distillation of cold-pressed peel oils of Citrus sinensis. After development of a liquid chromatographic separation procedure, the presence of several polymethoxy flavones such as sinensetin, nobiletin, tangeretin, quercetogetin, heptamethoxyflavone, and other derivatives was unambiguously confirmed. In addition, proceranone, an acetylated tetranortriterpenoid with limonoid structure, was identified for the first time in citrus.
引用
收藏
页码：274 / 278
页数：5
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