CO2 capture by a task-specific ionic liquid

被引:1983
|
作者
Bates, ED [1 ]
Mayton, RD [1 ]
Ntai, I [1 ]
Davis, JH [1 ]
机构
[1] Univ S Alabama, Dept Chem, Mobile, AL 36688 USA
关键词
D O I
10.1021/ja017593d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of 1-butyl imidazole with 3-bromopropylamine hydrobromide, followed by workup and anion exchange, yields a new room temperature ionic liquid incorporating a cation with an appended amine group. The new ionic liquid reacts reversibly with CO2, reversibly sequestering the gas as a carbamate salt. The new ionic liquid, which can be repeatedly recycled in this role, is comparable in efficiency for CO2 capture to commercial amine sequestering reagents, and yet is nonvolatile and does not require water to function. Copyright © 2002 American Chemical Society.
引用
收藏
页码:926 / 927
页数:2
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