Hybrid supercapacitor devices based on MnCo2O4 as the positive electrode and FeMn2O4 as the negative electrode

被引:144
作者
Nagamuthu, Sadayappan [1 ]
Vijayakumar, Subbukalai [1 ]
Lee, Seong-Hun [1 ]
Ryu, Kwang-Sun [1 ]
机构
[1] Univ Ulsan, Dept Chem, Ulsan 680749, South Korea
基金
新加坡国家研究基金会;
关键词
MnCo2O4; FeMn2O4; Nanosheets; Hybrid supercapacitor; Negative electrode; ELECTROCHEMICAL ENERGY-STORAGE; HIGH-PERFORMANCE; ASYMMETRIC SUPERCAPACITORS; EFFICIENT SUPERCAPACITOR; NANOCOMPOSITE FILM; MESOPOROUS MNCO2O4; SPINEL MNCO2O4; ION BATTERIES; OXIDE; GRAPHENE;
D O I
10.1016/j.apsusc.2016.08.072
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
MnCo2O4 nanosheets and FeMn2O4 nanospheres were synthesized using a hydrothermal method. Choline chloride was used as the capping agent during the preparation of the nanoparticles. XRD patterns confirmed the spinel structure of MnCo2O4 and FeMn2O4. XPS measurements were used to determine the oxidation state of the prepared spinel metal oxides. HRTEM images revealed the formation of hexagonal nanosheets of MnCo2O4 and nanospheres of FeMn2O4. Electrochemical measurements were made for both positive and negative electrodes using three electrode systems. MnCo2O4 Exhibits 282C g(-1) and FeMn2O4 yields 110C g(-1) at a specific current of 1A g(-1). Hybrid supercapacitor device was fabricated using MnCo2O4 as the positive and FeMn2O4 as the negative electrode material. The hybrid supercapacitor device was delivered a maximum power of 37.57 kW kg(-1). (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:202 / 208
页数:7
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