Creation of Bronsted acid sites on Sn-based solid catalysts for the conversion of biomass

被引：49

作者：

Wang, Liang ^{[1
]}

Zhang, Jian ^{[1
]}

Wang, Xuefeng ^{[2
,7
]}

Zhang, Bingsen ^{[4
]}

Ji, Weijie ^{[5
]}

Meng, Xiangju ^{[1
]}

Li, Jixue ^{[6
]}

Su, Dang Sheng ^{[3
,4
]}

Bao, Xinhe ^{[2
]}

Xiao, Feng-Shou ^{[1
]}

机构：

[1] Zhejiang Univ, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[3] Max Planck Gesell, Dept Inorgan Chem, Fritz Haber Inst, D-14195 Berlin, Germany

[4] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China

[5] Nanjing Univ, Key Lab Mesoscop Chem, MOE, Dept Chem, Nanjing 210093, Jiangsu, Peoples R China

[6] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310028, Peoples R China

[7] Dalian Univ, Sch Environm & Chem Engeering, Dalian 116622, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 11期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

SBA-15 MESOPOROUS MATERIALS; SUPPORTED METAL-CLUSTERS; MOLECULAR-SIEVES; ZEOLITE CATALYST; AQUEOUS-MEDIA; LACTIC-ACID; LEWIS; GLYCEROL; WATER; FRUCTOSE;

D O I：

10.1039/c3ta14982j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydroxyl-attached Sn species are highly dispersed on the surface of mesoporous silica (SBA-15) by the grafting of dimethyldichlorostannane followed by calcination to transform the methyl groups into hydroxyl groups (S-Sn-OH). S-Sn-OH has both Lewis and Bronsted acidic sites, resulting in superior catalytic activities in the acetalisation of glycerol.

引用

页码：3725 / 3729

页数：5

共 62 条

[1] Ion Exchange Resins: Catalyst Recovery and Recycle
Barbaro, Pierluigi
Liguori, Francesca
[J]. CHEMICAL REVIEWS, 2009, 109 (02) : 515 - 529
[2] Oils and Fats as Renewable Raw Materials in Chemistry
Biermann, Ursula
Bornscheuer, Uwe
Meier, Michael A. R.
Metzger, Juergen O.
Schaefer, Hans J.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (17) : 3854 - 3871
[3] Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals
Binder, Joseph B.
Raines, Ronald T.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) : 1979 - 1985
[4] Acid catalysts in industrial hydrocarbon chemistry
Busca, Guido
[J]. CHEMICAL REVIEWS, 2007, 107 (11) : 5366 - 5410
[5] Sustainable production of acrolein:: gas-phase dehydration of glycerol over 12-tungstophosphoric acid supported on ZrO2 and SiO2
Chai, Song-Hai
Wang, Hao-Peng
Liang, Yu
Xu, Bo-Qing
[J]. GREEN CHEMISTRY, 2008, 10 (10) : 1087 - 1093
[6] Direct Preparation of Thermally Stable Sn-Incorporated SBA-15 Mesoporous Materials in the Self-Generated Acidic Environment
Chen, Shih-Yuan
Tsai, Huai-De
Chuang, Wei-Tsung
Lee, Jey-Jau
Tang, Chih-Yuan
Lin, Ching-Yen
Cheng, Soofin
[J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (34) : 15226 - 15238
[7] Activation of ethane in the presence of solid acids: Sulfated zirconia, iron- and manganese-promoted sulfated zirconia, and zeolites
Cheung, TK
Gates, BC
[J]. JOURNAL OF CATALYSIS, 1997, 168 (02) : 522 - 531
[8] Insights into the Interplay of Lewis and Bronsted Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural and Levulinic Acid in Aqueous Media
Choudhary, Vinit
Mushrif, Samir H.
Ho, Christopher
Anderko, Andrzej
Nikolakis, Vladimiros
Marinkovic, Nebojsa S.
Frenkel, Anatoly I.
Sandler, Stanley I.
Vlachos, Dionisios G.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (10) : 3997 - 4006
[9] Xylose Isomerization to Xylulose and its Dehydration to Furfural in Aqueous Media
Choudhary, Vinit
Pinar, Ana B.
Sandler, Stanley I.
Vlachos, Dionisios G.
Lobo, Raul F.
[J]. ACS CATALYSIS, 2011, 1 (12): : 1724 - 1728
[10] Lewis acids:: From conventional homogeneous to green homogeneous and heterogeneous catalysis
Corma, A
García, H
[J]. CHEMICAL REVIEWS, 2003, 103 (11) : 4307 - 4365

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