Tetrachloridometallate Dianion-Induced Cucurbit[8]uril Supramolecular Assemblies with Large Channels and Their Potential Applications for Extraction Coating on Solid-Phase Microextraction Fibers

被引：29

作者：

Ji, Ning-Ning ^{[1
]}

Cheng, Xiao-Jie ^{[1
]}

Zhao, Yi ^{[1
]}

Liang, Li-Li ^{[1
]}

Ni, Xin-Long ^{[1
]}

Xiao, Xin ^{[1
]}

Zhu, Qian-Jiang ^{[1
]}

Xue, Sai-Feng ^{[1
]}

Dong, Nan ^{[1
]}

Tao, Zhu ^{[1
]}

机构：

[1] Guizhou Univ, Key Lab Macrocycl & Supramol Chem Guizhou Prov, Guiyang 550025, Peoples R China

来源：

INORGANIC CHEMISTRY | 2014年 / 53卷 / 01期

基金：

中国国家自然科学基金;

关键词：

CUCURBITURIL; COMPLEXES; CHEMISTRY; COORDINATION; SORPTION;

D O I：

10.1021/ic4025684

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Q[8]-based porous materials were synthesized in the presence of [Md-blockCl4](2-) anions as structure inducers. The driving forces of the structure-directing effect of the [Md-blockCl4](2-) anions may be due to the ion-dipole interaction and hydrogen bonding between the [Md-blockCl4](2-) anions and CH or =CH2 groups on the backs of Q[8] molecules. Moreover, the tests of potential applications show that these porous materials can not only capture organic molecules through the cavity of Q[8] moieties but also adsorb larger organic molecules with different selectivities.

引用

页码：21 / 23

页数：3

共 46 条

[1] A facile method for preparing one-molecule-thick free-standing organic nanosheets with a regular square shape [J].

An, Qi ;

Chen, Qing ;

Zhu, Wei ;

Li, Yan ;

Tao, Cheng-an ;

Yang, Haowei ;

Li, Zhanping ;

Wan, Lijun ;

Tian, He ;

Li, Guangtao .

CHEMICAL COMMUNICATIONS, 2010, 46 (05) :725-727

[2] Highly symmetric columnar channels in metal-free cucurbit[n] uril hydrate crystals (n = 6, 8) [J].

Bardelang, David ;

Udachin, Konstantin A. ;

Leek, Donald M. ;

Ripmeester, John A. .

CRYSTENGCOMM, 2007, 9 (11) :973-975

[3] Twisted Cucurbit[14]uril [J].

Cheng, Xiao-Jie ;

Liang, Li-Li ;

Chen, Kai ;

Ji, Ning-Ning ;

Xiao, Xin ;

Zhang, Jian-Xin ;

Zhang, Yun-Qian ;

Xue, Sai-Feng ;

Zhu, Qian-Jiang ;

Ni, Xin-Long ;

Tao, Zhu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (28) :7252-7255

[4] Direct coordination of metal ions to cucurbit[n]urils [J].

Cong Hang ;

Zhu QianJiang ;

Xue SaiFeng ;

Tao Zhu ;

Wei Gang .

CHINESE SCIENCE BULLETIN, 2010, 55 (32) :3633-3640

[5]

Day A.I., 2000, Patent, Patent No. [68232, WO0068232, 0068232]

[6]

Day AI, 2002, ANGEW CHEM INT EDIT, V41, P275, DOI 10.1002/1521-3773(20020118)41:2<275::AID-ANIE275>3.0.CO

[7]

2-M

[8] Cucurbit[n]uril-Polyoxoanion Hybrids [J].

Fang, Xikui ;

Koegerler, Paul ;

Isaacs, Lyle ;

Uchida, Sayaka ;

Mizuno, Noritaka .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (02) :432-+

[9] New lines of research in chemistry of chalcogenide complexes: From clusters to supramolecular compounds [J].

Fedin, VP .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2004, 30 (03) :151-158

[10] CUCURBITURIL [J].

FREEMAN, WA ;

MOCK, WL ;

SHIH, NY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (24) :7367-7368

← 1 2 3 4 5 →