Intrinsic properties of metal-organic frameworks (MOFs) in supercapacitor applications

被引:39
作者
Makgopa, Katlego [1 ]
Ratsoma, Mpho S. [1 ]
Modibane, Kwena D. [2 ]
机构
[1] Tshwane Univ Technol, Fac Sci, Dept Chem, Arcadia Campus, ZA-0001 Pretoria, South Africa
[2] Univ Limpopo Turfloop, Sch Phys & Mineral Sci, Dept Chem, ZA-0727 Sovenga, Polokwane, South Africa
基金
新加坡国家研究基金会;
关键词
Supercapacitors; Capacitive type; Metal-organic frameworks; Pseudocapacitive; Battery type; ENERGY-STORAGE; ELECTRODE MATERIALS; PERFORMANCE; NANOCOMPOSITES; NANOMATERIALS; NANORODS;
D O I
10.1016/j.coelec.2022.101112
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The need to optimize the performance of energy storage systems has driven the search for new materials showing inherent properties that are favorable in enhancing energy and power outputs. Recently, metal-organic frameworks (MOFs) have emerged as promising materials because of their desir-able features that include rich redox metal centers, rapid ion transport, ultrahigh and tunable porosity, and large surface areas that offer maximized electroactive sites. The electro-chemical performance of MOFs depends on their architecture (0D-3D) and morphology (micro-or nanostructure), which are determined by the design and synthesis of these electrode materials. The highlight of this review is to demonstrate the outstanding findings from the literature on the use of MOFs as robust electrode materials with distinct charge storage behavior in supercapacitor applications.
引用
收藏
页数:9
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