Chiral Lewis acid catalysts in Diels-Alder cycloadditions: Mechanistic aspects and synthetic applications of recent systems

被引：189

作者：

Dias, LC ^{[1
]}

机构：

[1] UNIV ESTADUAL CAMPINAS, UNICAMP, INST QUIM, BR-13083970 CAMPINAS, SP, BRAZIL

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 1997年 / 8卷 / 04期

关键词：

asymmetric Diels-Alder cycloaddition reaction; chiral Lewis acids; asymmetric catalysis; dienophile-Lewis acid complex;

D O I：

10.1590/S0103-50531997000400002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review summarizes the recent progress which has been made in the use of chiral Lewis Acid catalysts in Diels-Alder cycloaddition reactions. Chiral catalysts containing aluminum, boron, titanium, copper, lanthanides, magnesium and transition-metals are critically reviewed. Structural studies on Lewis acid carbonyl complexes and synthetic applications of recent systems are specifically discussed.

引用

页码：289 / 332

页数：44

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