Highly Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Diynes to Sulfonimines

被引：58

作者：

Amatore, Muriel ^{[1
]}

Leboeuf, David ^{[1
]}

Malacria, Max ^{[1
]}

Gandon, Vincent ^{[1
]}

Aubert, Corinne ^{[1
]}

机构：

[1] Univ Paris 06, UMR CNRS 7201, Inst Parisien Chim Mol, F-75252 Paris 05, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 12期

关键词：

STEREOSELECTIVE-SYNTHESIS; ALKYNES; DIHYDROPYRIDINES; 1,2-DIHYDROPYRIDINES; COMPLEXES; PYRIDINES; CYCLOTRIMERIZATION; CONSTRUCTION; HETEROCYCLES; CHEMISTRY;

D O I：

10.1021/ja309301n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new asymmetric [2+2+2] cycloaddition of diynes to sulfonimines under rhodium catalysis that provides the corresponding enantioenriched 1,2-dihydropyridines in good yields is described.

引用

页码：4576 / 4579

页数：4

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