A new synthetic route for 1,2-diketo compounds using unexpected C-C bond cleavage by PCC

被引：8

作者：

Bhosale, Shrikar M. ^{[1
]}

Momin, Aadil A. ^{[1
]}

Gawade, Rupesh L. ^{[2
]}

Puranik, Vedavati G. ^{[2
]}

Kusurkar, Radhika S. ^{[1
]}

机构：

[1] Univ Pune, Dept Chem, Pune 411007, Maharashtra, India

[2] Natl Chem Lab, Pune 411008, Maharashtra, India

来源：

TETRAHEDRON LETTERS | 2012年 / 53卷 / 39期

关键词：

1,2-Diketones; PCC; C-C bond cleavage; PYRIDINIUM CHLOROCHROMATE; OXIDATIVE CLEAVAGE; STEREOSELECTIVE-SYNTHESIS; HYDROGEN-PEROXIDE; CONVENIENT; ALDEHYDES; ALCOHOLS; KETONES; INTERMEDIATE; METHODOLOGY;

D O I：

10.1016/j.tetlet.2012.07.095

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method has been established for the preparation of 1,2-diketones by unexpected C-C bond cleavage in 4-keto-2-hydroxy esters using pyridiniumchlorochromate (PCC). (c) 2012 Elsevier Ltd. All rights reserved.

引用

页码：5327 / 5330

页数：4

共 68 条

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