Soluble Polymers as Tools in Catalysis

被引:61
作者
Bergbreiter, David E. [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
基金
美国国家科学基金会;
关键词
GRUBBS CATALYST; POLYMERIZATION; TEMPERATURE; SUPPORTS; POLYETHYLENE; PARAFFIN; LIGANDS; NANOPARTICLES; METHACRYLATE; PEG;
D O I
10.1021/mz500075b
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Examples where soluble polymers have been used in homogeneous catalysis were first noted 50 years ago, but this role for soluble polymers remained relatively unexplored until the 1990s. Since then, the use of new polymers, new developments in polymer synthesis, new separation strategies, and the imaginative ways soluble polymers' structure and physical properties can be used to influence a covalent or ligated catalyst have led to increasing interest in soluble polymers as tools in catalysis.
引用
收藏
页码:260 / 265
页数:6
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共 60 条
[1]   Enhanced Catalyst Activity and Enantioselectivity with Chirality-Switchable Polymer Ligand PQXphos in Pd-Catalyzed Asymmetric Silaborative Cleavage of meso-Methylenecyclopropanes [J].
Akai, Yuto ;
Yamamoto, Takeshi ;
Nagata, Yuuya ;
Ohmura, Toshimichi ;
Suginome, Michinori .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (27) :11092-11095
[2]   A phase-separable second-generation hoveyda-grubbs catalyst for ring-opening metathesis polymerization [J].
Al-Hashimi, Mohammed ;
Hongfa, Chayanant ;
George, Beena ;
Bazzi, Hassan S. ;
Bergbreiter, David E. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (19) :3954-3959
[3]   Developing a Synthetic Approach with Thermoregulated Phase-Transfer Catalysis: Facile Access to Metal-Mediated Living Radical Polymerization of Methyl Methacrylate in Aqueous/Organic Biphasic System [J].
Bai, Liangjiu ;
Zhang, Lifen ;
Pan, Jinlong ;
Zhu, Jian ;
Cheng, Zhenping ;
Zhu, Xiulin .
MACROMOLECULES, 2013, 46 (06) :2060-2066
[4]  
Baker Hughes Inc, POL
[5]   SOLUBLE METAL-COMPLEXES OF POLYMERS FOR CATALYSIS [J].
BAYER, E ;
SCHURIG, V .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (07) :493-494
[6]   Recyclable polyisobutylene-supported pyridyl N-oxide allylation catalysts [J].
Bergbreiter, David E. ;
Ortiz-Acosta, Denisse .
TETRAHEDRON LETTERS, 2008, 49 (39) :5608-5610
[7]   A combinatorial approach to studying the effects of N-alkyl groups on poly(N-alkyl and N,N-dialkylacrylamide) solubility [J].
Bergbreiter, David E. ;
Aviles-Ramos, Nydea A. ;
Ortiz-Acosta, Denisse .
JOURNAL OF COMBINATORIAL CHEMISTRY, 2007, 9 (04) :609-617
[8]   Soluble polyisobutylene-supported reusable catalysts for olefin cyclopropanation [J].
Bergbreiter, David E. ;
Tian, Jianhua .
TETRAHEDRON LETTERS, 2007, 48 (26) :4499-4503
[9]   Variable-Temperature NMR Studies of Soluble Polymer-Supported Phosphine-Silver Complexes [J].
Bergbreiter, David E. ;
Yang, Yun-Chin .
JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (03) :873-878
[10]   Using Soluble Polymer Supports To Facilitate Homogeneous Catalysis [J].
Bergbreiter, David E. ;
Tian, Jianhua ;
Hongfa, Chayanant .
CHEMICAL REVIEWS, 2009, 109 (02) :530-582