Highly Efficient Catalytic Dimerization of Styrenes via Cationic Palladium(II) Complexes

被引：22

作者：

Choi, Ji Hye ^{[1
,2
]}

Kwon, Jae Kwan ^{[1
]}

RajanBabu, T. V. ^{[3
]}

Lim, Hwan Jung ^{[1
]}

机构：

[1] Korea Res Inst Chem Technol, Med Chem Res Ctr, Taejon 305345, South Korea

[2] Hanyang Univ, Dept Chem, Seoul 133791, South Korea

[3] Ohio State Univ, Dept Chem & Biochem, Columbus, OH 43210 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 18期

基金：

美国国家科学基金会;

关键词：

CC bond formation; dimerization; palladium hydride; styrene; ASYMMETRIC HYDROVINYLATION; NICKEL-COMPLEXES; SELECTIVE TRIMERIZATION; ETHYLENE; ROUTE; OLIGOMERIZATION; LIGANDS; ETHENE; CODIMERIZATION; ISOMERIZATION;

D O I：

10.1002/adsc.201300864

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A highly efficient head-to-tail dimerization of a styrene was developed using a cationic palladium(II)-catalyzed selective CC bond forming reaction. The complex [AllylPd(PPh3)]+OTf-, which is believed to generate palladium hydride' (PdH), catalyzed the dimerization of various styrenes in excellent yields as single isomers. This Pd(II)-catalyzed reaction provides a new economical CC bond forming method.

引用

页码：3633 / 3638

页数：6

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