Twofold Carbon-Carbon Bond Formation by Intra- and Intermolecular Radical Reactions of Aryl Diazonium Salts

被引：33

作者：

Jasch, Hannelore ^{[1
]}

Landais, Yannick ^{[2
]}

Heinrich, Markus R. ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91052 Erlangen, Germany

[2] Univ Bordeaux 1, CNRS, Inst Mol Sci, UMR 5255, F-33405 Talence, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 26期

关键词：

aryl radicals; carbon-carbon bond formation; cascade reactions; cyclization; radical reactions; CONJUGATE-ADDITION-REACTIONS; C-H ARYLATION; NONACTIVATED OLEFINS; METAL-FREE; REDUCTIVE CARBODIAZENYLATION; ARENEDIAZONIUM SALTS; TRIBUTYLTIN HYDRIDE; SODIUM-BOROHYDRIDE; ORTHO-SUBSTITUENTS; ELECTRON-DONOR;

D O I：

10.1002/chem.201300354

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cascade reactions: A variety of novel cascade reactions can be performed when the known and well-studied radical 5- or 6-exo-cyclization of an aryl diazonium salt is conducted in the presence of alkenes and further optional scavengers (see scheme). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8411 / 8416

页数：6

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