Twofold Carbon-Carbon Bond Formation by Intra- and Intermolecular Radical Reactions of Aryl Diazonium Salts

被引：33
|
作者：
Jasch, Hannelore [1 ]
Landais, Yannick [2 ]
Heinrich, Markus R. [1 ]
机构：
[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91052 Erlangen, Germany
[2] Univ Bordeaux 1, CNRS, Inst Mol Sci, UMR 5255, F-33405 Talence, France
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 26期
关键词：
aryl radicals; carbon-carbon bond formation; cascade reactions; cyclization; radical reactions; CONJUGATE-ADDITION-REACTIONS; C-H ARYLATION; NONACTIVATED OLEFINS; METAL-FREE; REDUCTIVE CARBODIAZENYLATION; ARENEDIAZONIUM SALTS; TRIBUTYLTIN HYDRIDE; SODIUM-BOROHYDRIDE; ORTHO-SUBSTITUENTS; ELECTRON-DONOR;
D O I：
10.1002/chem.201300354
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cascade reactions: A variety of novel cascade reactions can be performed when the known and well-studied radical 5- or 6-exo-cyclization of an aryl diazonium salt is conducted in the presence of alkenes and further optional scavengers (see scheme). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8411 / 8416
页数：6
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