Local structure and time-resolved photoluminescence of emulsion prepared YAG nanoparticles

被引:42
作者
Furman, J. D. [1 ]
Gundiah, G. [2 ]
Page, K. [3 ]
Pizarro, N. [4 ]
Cheetham, A. K. [1 ]
机构
[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
[2] Univ Calif Santa Barbara, Mitsubishi Chem Ctr Adv Mat, Santa Barbara, CA 93106 USA
[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[4] Univ Andres Bello, Fac Ecol & Recursos Nat, Dept Ciencias Quim, Santiago, Chile
关键词
D O I
10.1016/j.cplett.2008.09.045
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
White LEDs rely on phosphors to convert blue or UV light into the broad spectrum emission needed for illumination. Nanoparticles of the Ce-doped yttrium aluminum garnet (YAG:Ce3+) phosphor were prepared by an emulsion route and calcined at various temperatures. The products were characterized by X-ray diffractometry, electron microscopy, and photoluminescence measurements, as well as time-resolved luminescent measurements at different temperatures (77-473 K). Quantitative Rietveld refinement with decreasing calcination temperatures and pair distribution function analyses, carried out with synchrotron X-ray data, revealed both luminescence quenching impurity phases and reduced long range correlation. (c) 2008 Published by Elsevier B.V. .
引用
收藏
页码:67 / 72
页数:6
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