Influence of stirring speed on the suspension copolymerization of styrene with methyl methacrylate

被引：7

作者：

Cordovi, CM

DeLucas, A

Rodriguez, JF

Tejeda, J

机构：

[1] UNIV CASTILLA LA MANCHA,FAC CHEM,DEPT CHEM ENGN,CIUDAD REAL 13004,SPAIN

[2] UNIV CASTILLA LA MANCHA,FAC CHEM,DEPT ORGAN INORGAN & BIOCHEM,CIUDAD REAL 13004,SPAIN

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1997年 / A34卷 / 08期

关键词：

D O I：

10.1080/10601329708011048

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The influence of stirring rate on the suspension copolymerization of methyl methacrylate-styrene system was studied. A significant growth of particle size during the copolymerization reaction takes place. It was found that the increase of stirring rate produces a reduction of particle size, being possible to relate the final average particle size to the stirring rate. The kinetic of copolymerization reaction corresponds to that of bulk free radical initiated polymerization and it is not affected by the stirring rate. Copolymerization composition and average molecular weight distribution are in reasonable agreement with the data reported in the literature for the same monomer systems in bulk polymerization. This copolymer shows enhanced thermal stability compared to methyl methacrylate polymers.

引用

页码：1339 / 1351

页数：13

共 22 条

[1] A POPULATION BALANCE APPROACH FOR THE DESCRIPTION OF PARTICLE-SIZE DISTRIBUTION IN SUSPENSION POLYMERIZATION REACTORS [J].