Eremostachiin:: a new furanolabdane diterpene glycoside from Eremostachys glabra

被引:35
|
作者
Delazar, A
Modarresi, M
Shoeb, M
Nahar, L
Reid, RG
Kumarasamy, Y
Majinda, RRT
Sarker, SD
机构
[1] Univ Ulster, Sch Biomed Sci, Coleraine BT52 1SA, Londonderry, North Ireland
[2] Tabriz Univ Med Sci, Sch Pharm, Tabriz, Iran
[3] Robert Gordon Univ, Sch Pharm, Phytopharmaceut Res Lab, Aberdeen AB10 1FR, Scotland
[4] Robert Gordon Univ, Sch Life Sci, Aberdeen AB25 1HG, Scotland
[5] Univ Botswana, Fac Sci, Dept Chem, Gaborone, Botswana
关键词
Eremostachys glabra; Labiatae; Lamiaceae; eremostachiin; furanolabdane; diterpene; DPPH; antioxidant;
D O I
10.1080/13518470500047082
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The reversed-phase preparative HPLC analysis of the methanol extract of the rhizomes of Eremostachys glabra (Lamiaceae) led to the isolation of two furanolabdane diterpene glycosides, phlomisoside II, and beta-D-glucopyranosyl-(1 -> 2)-beta-D-glucopyranosyl ester of phlomisoic acid (named eremostachiin), the latter being a novel natural product. The structure of the new compound has been elucidated unambiguously by HRMS and a series of 1D- and 2D-NMR spectroscopic techniques. The free radical scavenging activity of these compounds was assessed using the DPPH assay.
引用
收藏
页码:167 / 172
页数:6
相关论文
共 50 条
  • [41] Rebaudioside F, a diterpene glycoside from Stevia rebaudiana
    Starratt, AN
    Kirby, CW
    Pocs, R
    Brandle, JE
    PHYTOCHEMISTRY, 2002, 59 (04) : 367 - 370
  • [42] Vicarin, a new isoflavone from Eremostachys vicaryi
    Imran, Muhammad
    Mehmood, Rashad
    Mughal, Uzma Rasheed
    Ali, Bakhat
    Malik, Abdul
    JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH, 2012, 14 (03) : 293 - 296
  • [43] A New Diterpene Glycoside: 15α-Hydroxy-Rebaudioside M Isolated from Stevia rebaudiana
    Prakash, Indra
    Ma, Gil
    Bunders, Cynthia
    Devkota, Krishna P.
    Charan, Romila D.
    Ramirez, Catherine
    Snyder, Tara M.
    Priedemann, Christopher
    NATURAL PRODUCT COMMUNICATIONS, 2015, 10 (07) : 1159 - 1161
  • [44] A New Diterpene: Abietane Glycoside from the Roots of Isodon rugosus Wall Ex Benth.
    Ullah, Arif
    Uddin, Ghias
    Rashid, Mamoon Ur
    Ismail, Ismail
    Nasruddin, Nasrudddin
    Siddiqui, Bina Shaheen
    Ullah, Zahoor
    Alamzeb, Muhammad
    RECORDS OF NATURAL PRODUCTS, 2019, 13 (04) : 287 - 295
  • [45] A DITERPENE GLYCOSIDE AND LIGNANS FROM SEED OF THUJOPSIS-DOLABRATA
    HASEGAWA, S
    HIROSE, Y
    PHYTOCHEMISTRY, 1980, 19 (11) : 2479 - 2481
  • [46] A diterpene, a sesquiterpene and a flavonol glycoside from Piptostigma fasciculata (Annonaceae)
    Seidel, V
    Bailleul, F
    Waterman, PG
    BIOCHEMICAL SYSTEMATICS AND ECOLOGY, 1999, 27 (05) : 543 - 545
  • [47] A LABDANE DITERPENE AND ITS GLYCOSIDE FROM MELODINUS-MONOGYNUS
    SETHI, A
    KHARE, A
    KHARE, MP
    PHYTOCHEMISTRY, 1988, 27 (07) : 2255 - 2259
  • [48] Loasifolin, a new flavonoid from Eremostachys loasifolia
    Mughal, Uzma Rasheed
    Fatima, Itrat
    Malik, Abdul
    Tareen, Rasool Bakhsh
    JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH, 2010, 12 (04) : 328 - 330
  • [49] Iwayoside A, a New Diterpene Glycoside from Artemisia iwayomogi Kitamura that Enhances IL-2 Secretion
    Ding, Yan
    Liang, Chun
    Yang, Seo Young
    Kim, Jun Ho
    Lee, Young Mi
    Kim, Young Ho
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2010, 31 (08): : 2422 - 2423
  • [50] A new glycoside and a novel-type diterpene from Hemerocallis fulva (L.) L.
    Yang, ZD
    Chen, H
    Li, YC
    HELVETICA CHIMICA ACTA, 2003, 86 (10) : 3305 - 3309