Non-Isothermal Crystallization of Poly(Vinylidenefluoride)/Hollow Glass Microspheres Composites

被引：11

作者：

Li, Jun-wei ^{[1
,2
]}

Xu, Xin-hua ^{[1
]}

机构：

[1] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China

[2] Tianjin Inst Urban Construct, Dept Mat Sci & Engn, Tianjin, Peoples R China

来源：

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2012年 / 51卷 / 12期

关键词：

Composites; Crystallization kinetic; Hollow glass microspheres; Non-isothermal crystallization; Poly (vinylidene fluoride); POLY(VINYLIDENE FLUORIDE); PHASE-TRANSFORMATION; KINETICS; BEHAVIOR; NANOCOMPOSITES; PVDF; PARAMETERS; BEADS; FILMS;

D O I：

10.1080/03602559.2012.696761

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The Poly(vinylidene fluoride)/Hollow glass microspheres(PVDF/HGMs) composites were prepared by the method of solution blending. The non-isothermal crystallization of the PVDF and its composites were investigated with a differential scanning calorimeter (DSC). The results showed that the crystallization peaks shifted to a lower temperature and became wider with an increasing cooling rate. The HGMs caused to increase in crystallization temperature and initial crystallization temperature. In addition, the Jeziorny and the Mo methods were used to analyze the non-isothermal crystallization kinetics. The results showed that the crystallization rate rose with the cooling rate rising, however, the HGMs decreased the crystallization rates of the PVDF.

引用

页码：1204 / 1208

页数：5

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