Synthesis of polycrystalline SnO2 nanotubes on carbon nanotube template for anode material of lithium-ion battery

被引:62
作者
Du, Ning
Zhang, Hui
Chen, Bindi
Ma, Xiangyang
Huang, Xiaohua
Tu, Jiangping
Yang, Deren [1 ]
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
关键词
Nanostructures; Semiconductors; Oxides; Chemical synthesis; Electrochemical properties; HIGH-CAPACITY; ELECTROCHEMICAL PROPERTIES; ALPHA-FE2O3; NANOTUBES; OXIDE NANOTUBES; NANOWIRES; STORAGE; ELECTRODES; NANOCOMPOSITES; NANOPARTICLES; PERFORMANCE;
D O I
10.1016/j.materresbull.2008.04.001
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polycrystalline tin oxide nanotubes have been prepared by a layer-by-layer technique on carbon nanotubes template. Firstly, the surface of carbon nanotubes was modified by polyelectrolyte. Then, a uniform layer of tin oxide nanoparticles was formed on the positive charged surface of carbon nanotubes via a redox process. At last, the polycrystalline tin oxide nanotubes were synthesized after calcination at 650 degrees C in air for 3 h. The as-synthesized polycrystalline nanotubes with large surface area exhibit finer lithium storage capacity and cycling performance, which shows the potentially interesting application in lithium-ion battery. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:211 / 215
页数:5
相关论文
共 35 条
[1]   Investigation of the structural and electrochemical properties of size-controlled SnO2 nanoparticles [J].
Ahn, HJ ;
Choi, HC ;
Park, KW ;
Kim, SB ;
Sung, YE .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (28) :9815-9820
[2]   Nanostructured Li ion insertion electrodes. 2. Tin dioxide nanocrystalline layers and discussion on "nanoscale effect" [J].
Bueno, PR ;
Leite, ER ;
Giraldi, TR ;
Bulhoes, LOS ;
Longo, E .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (34) :8878-8883
[3]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[4]   Fabrication and characterization of nanotubular semiconductor oxides In2O3 and Ga2O3 [J].
Cheng, B ;
Samulski, ET .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (12) :2901-2902
[5]   Key factors controlling the reversibility of the reaction of lithium with SnO2 and Sn2BPO6 glass [J].
Courtney, IA ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (09) :2943-2948
[6]   Porous Co3O4 nanotubes derived from Co4(CO)12 clusters on carbon nanotube templates:: A highly efficient material for Li-battery applications [J].
Du, Ning ;
Zhang, Hui ;
Chen, Bindi ;
Wu, Jianbo ;
Ma, Xiangyang ;
Liu, Zhihong ;
Zhang, Yiqiang ;
Yang, Deren ;
Huang, Xiaohua ;
Tu, Jiangping .
ADVANCED MATERIALS, 2007, 19 (24) :4505-+
[7]   Porous indium oxide nanotubes:: Layer-by-layer assembly on carbon-nanotube templates and application for room-temperature NH3 gas sensors [J].
Du, Ning ;
Zhang, Hui ;
Chen, Bindi ;
Ma, Xiangyang ;
Liu, Zhihong ;
Wu, Jianbo ;
Yang, Deren .
ADVANCED MATERIALS, 2007, 19 (12) :1641-+
[8]   Ordered, nanostructured tin-based oxides/carbon composite as the negative-electrode material for lithium-ion batteries [J].
Fan, J ;
Wang, T ;
Yu, CZ ;
Tu, B ;
Jiang, ZY ;
Zhao, DY .
ADVANCED MATERIALS, 2004, 16 (16) :1432-+
[9]   Simple synthesis of hollow tin dioxide microspheres and their application to lithium-ion battery anodes [J].
Han, SJ ;
Jang, BC ;
Kim, T ;
Oh, SM ;
Hyeon, T .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (11) :1845-1850
[10]   Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397