2-[2-(dimethylamino)ethylammoniomethyl]-4-nitrophenolate

被引：10

作者：

Hazell, A ^{[1
]}

Overgaard, J ^{[1
]}

Lausen, SK ^{[1
]}

Hu, HJ ^{[1
]}

Khoo, LE ^{[1
]}

机构：

[1] NANYANG TECHNOL UNIV,SCH SCI,SINGAPORE 259756,SINGAPORE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270196015491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the title compound, C11H17N3O3, reveals that the intramolecular hydrogen-bonded phenolic H atom has shifted to the amino N atom so that there is an intermolecular hydrogen bond to the phenolic O atom of a neighbouring molecule [N ... O 2.644(3) Angstrom], as well as an intramolecular hydrogen bond [N ... O 2.662 (4) Angstrom]. This proton-transfer process is due to the nitro substituent which facilitates the formation of a quinonoid structure for the substituted phenyl ring.

引用

页码：640 / 641

页数：2

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