Electro-oxidation of methanol and ethanol using PtRu/C electrocatalysts prepared by spontaneous deposition of platinum on carbon-supported ruthenium nanoparticles

被引：142
|
作者：
Spinacé, E [1 ]
Neto, AO [1 ]
Linardi, M [1 ]
机构：
[1] Ctr Ciencia & Tecnol Mat, CNEN, IPEN, BR-05508900 Sao Paulo, Brazil
来源：
JOURNAL OF POWER SOURCES | 2004年 / 129卷 / 02期
基金：
巴西圣保罗研究基金会;
关键词：
electro-oxidation; ethanol; methanol; PtRu/C electrocatalyst; fuel cell; spontaneous deposition;
D O I：
10.1016/j.jpowsour.2003.11.056
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
PtRu/C electrocatalysts were prepared by spontaneous deposition of Pt(II) and Pt(IV) ions on carbon-supported ruthenium nanoparticles, characterized by EDAX, TEM, cyclic voltammetry and tested for methanol and ethanol oxidation using the thin porous coating technique. The spontaneous deposition of Pt(II) ions was about two times more effective than Pt(IV) ions. The electrocatalysts were active for methanol and ethanol oxidation. For methanol oxidation good performance was obtained with high platinum coverage and for ethanol oxidation with low platinum coverage. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：121 / 126
页数：6
相关论文
共 50 条
  • [11] Electro-oxidation of ethanol in acid medium using carbon-supported PtRh nanoparticles with (100) preferential orientation
    Pereira Filho, N. G.
    Souza, R. F. B.
    Ramos, A. S.
    Antoniassi, R. M.
    Neto, A. Oliveira
    Spinace, E., V
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2021, 16 (12):
  • [12] PtRu/C and PtRuBi/C Electrocatalysts Prepared in Two Different Ways by Borohydride Reduction for Ethanol Electro-Oxidation
    Brandalise, Michele
    Tusi, Marcelo Marques
    Piasentin, Ricardo Marcelo
    Linardi, Marcelo
    Spinace, Estevam Vitorio
    Oliveira Neto, Almir
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2010, 5 (01): : 39 - 45
  • [13] Uniformly dispersed carbon-supported bimetallic ruthenium-platinum electrocatalysts for the methanol oxidation reaction
    Zheng, Yuying
    Zhan, Hengtong
    Fang, Yanxiong
    Zeng, Jianhuang
    Liu, Hui
    Yang, Jun
    Liao, Shijun
    JOURNAL OF MATERIALS SCIENCE, 2017, 52 (06) : 3457 - 3466
  • [14] Comparative study of methanol adsorption and electro-oxidation on carbon-supported platinum in acidic and alkaline electrolytes
    Jing, Mingyi
    Jiang, Luhua
    Yi, Baolian
    Sun, Gongquan
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2013, 688 : 172 - 179
  • [15] Electro-oxidation of ethanol and ethylene glycol on carbon-supported nano-Pt and -PtRu catalyst in acid solution
    Chatterjee, Moitrayee
    Chatterjee, Abhik
    Ghosh, Susanta
    Basumallick, I.
    ELECTROCHIMICA ACTA, 2009, 54 (28) : 7299 - 7304
  • [16] Electro-oxidation of Carbon Monoxide and Methanol on Carbon-Supported Pt-Sn Nanoparticles: a DEMS Study
    Manzo-Robledo, A.
    Boucher, A. -C
    Pastor, E.
    Alonso-Vante, N.
    FUEL CELLS, 2003, 2 (02) : 109 - 116
  • [17] Electro-oxidation of ethylene glycol on PtRu/C and PtSn/C electrocatalysts prepared by alcohol-reduction process
    A.O. Neto
    T.R.R. Vasconcelos
    R.W.R.V. Da Silva
    M. Linardi
    E.V. Spinacé
    Journal of Applied Electrochemistry, 2005, 35 : 193 - 198
  • [18] Electro-oxidation of ethylene glycol on PtRu/C and PtSn/C electrocatalysts prepared by alcohol-reduction process
    Neto, AO
    Vasconcelos, TRR
    Da Silva, RWRV
    Linardi, M
    Spinacé, EV
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 2005, 35 (02) : 193 - 198
  • [19] Carbon-nanosphere-supported Pt nanoparticles for methanol and ethanol electro-oxidation in alkaline media
    Wang, Xue
    Hu, Chenguo
    Xiong, Yufeng
    Liu, Hong
    Du, Guojun
    He, Xiaoshan
    JOURNAL OF POWER SOURCES, 2011, 196 (04) : 1904 - 1908
  • [20] Methanol electrooxidation on platinum spontaneously deposited on unsupported and carbon-supported ruthenium nanoparticles
    Kuk, ST
    Wieckowski, A
    JOURNAL OF POWER SOURCES, 2005, 141 (01) : 1 - 7
12345