Novel Feature and Catalysis of Metal Oxide Supported Gold Nanop articles

被引：0
作者：
Hamasaki, Akiyuki [1 ,2 ]
Ishida, Tamao [1 ,2 ]
Tokunaga, Makoto [1 ,2 ,3 ]
机构：
[1] Kyushu Univ, Grad Sch Sci, Higashi Ku, Fukuoka 8128581, Japan
[2] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
[3] Int Res Ctr Mol Syst, Nishi Ku, Fukuoka 8190395, Japan
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2013年 / 71卷 / 05期
关键词：
gold nanoparticles; metal oxide supports; heterogeneous catalysts; hydrogenation; carbonylation; Fischer-Tropsch synthesis; FISCHER-TROPSCH SYNTHESIS; PAUSON-KHAND REACTION; ANTI-ASF DISTRIBUTION; CHEMOSELECTIVE HYDROGENATION; EXPERIMENTAL PROTOCOL; PHASE EPOXIDATION; NITRO-COMPOUNDS; NANOPARTICLES; PROPYLENE; PROMOTION;
D O I：
10.5059/yukigoseikyokaishi.71.443
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Gold nanoparticles are drawing great attention because of its interesting properties. Although a bulk gold is chemically inert, a nano-sized particles shows completely different characteristics. Therefore, applications of gold nanoparticles for organic transformations are wide-spreading in recent years. We have developed several organic reactions employing metal oxide supported gold nanoparticles. In these reactions, the catalysis are assumed not only by gold nanoparticles but an active species formed from oxide support depending on the reaction conditions. This phenomenon expands the capability of metal oxide supported gold nanoparticles since the catalysis can be modulated by employing a proper metal oxide support.
引用
收藏
页码：443 / 451
页数：9
相关论文
共 50 条
  • [1] Thermal promotion of the cobalt catalyzed intramolecular Pauson-Khand reaction - An alternative experimental protocol for cyclopentenone synthesis
    Belanger, DB
    O'Mahony, DJR
    Livinghouse, T
    [J]. TETRAHEDRON LETTERS, 1998, 39 (42) : 7637 - 7640
  • [2] A molecular mechanism for the chemoselective hydrogenation of substituted nitroaromatics with nanoparticles of gold on TiO2 catalysts:: A cooperative effect between gold and the support
    Boronat, Merce
    Concepcion, Patricia
    Corma, Avelino
    Gonzalez, Silvia
    Illas, Francesc
    Serna, Pedro
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (51) : 16230 - 16237
  • [3] On the effect of water during Fischer-Tropsch synthesis with a ruthenium catalyst
    Claeys, M
    van Steen, E
    [J]. CATALYSIS TODAY, 2002, 71 (3-4) : 419 - 427
  • [4] Supported gold nanoparticles as catalysts for organic reactions
    Corma, Avelino
    Garcia, Hermenegildo
    [J]. CHEMICAL SOCIETY REVIEWS, 2008, 37 (09) : 2096 - 2126
  • [5] A different reaction pathway for the reduction of aromatic nitro compounds on gold catalysts
    Corma, Avelino
    Concepcion, Patricia
    Serna, Pedro
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) : 7266 - 7269
  • [6] Chemoselective hydrogenation of nitro compounds with supported gold catalysts
    Corma, Avelino
    Serna, Pedro
    [J]. SCIENCE, 2006, 313 (5785) : 332 - 334
  • [7] PREPARATION OF METHYL BETA-HYDROXYBUTYRATE FROM PROPYLENE OXIDE, CARBON MONOXIDE, METHANOL, AND DICOBALT OCTACARBONYL
    EISENMANN, J
    YAMARTINO, RL
    HOWARD, JF
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (06) : 2102 - &
  • [8] The Pauson-Khand reaction: the catalytic age is here!
    Gibson, SE
    Stevenazzi, A
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (16) : 1800 - 1810
  • [9] Cobalt oxide supported gold nanoparticles as a stable and readily-prepared precursor for the in situ generation of cobalt carbonyl like species
    Hamasaki, Akiyuki
    Muto, Akiko
    Haraguchi, Shingo
    Liu, Xiaohao
    Sakakibara, Takanori
    Yokoyama, Takushi
    Tokunaga, Makoto
    [J]. TETRAHEDRON LETTERS, 2011, 52 (51) : 6869 - 6872
  • [10] Amidocarbonylation of Aldehydes Utilizing Cobalt Oxide-supported Gold Nanoparticles as a Heterogeneous Catalyst
    Hamasaki, Akiyuki
    Liu, Xiaohao
    Tokunaga, Makoto
    [J]. CHEMISTRY LETTERS, 2008, 37 (12) : 1292 - 1293
12345