Corrosion Mitigation by an Eco-Friendly Inhibitor: Nerium Oleander Leaf Extract on Carbon Steel in an Acidic Medium

被引:1
作者
Selvi, J. Arockia [1 ]
Arthanareeswari, M. [1 ]
Kamaraj, P. [2 ]
Malini, T. Pushpa [1 ]
Elumalai, V [3 ]
Revathi, S. [1 ]
Subasree, N. [1 ]
机构
[1] SRM Inst Sci & Technol, Dept Chem, Kattankulathur 603203, India
[2] Vel Tech Rangarajan Dr Sanguthala R&D Inst Sci &, Dept Chem, Avad I 600002, India
[3] Univ Pittsburgh, Chevron Sci Ctr, Dept Chem, POB 15260, Pittsburgh, PA 15260 USA
关键词
carbon steel; corrosion inhibition; Nerium oleander leaf extract; electrochemical techniques; MILD-STEEL; TEMPERATURE;
D O I
10.4152/pea.202006387
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The inhibitory activity of ethanol extract of Nerium oleander leaf (NOLE) on carbon steel corrosion in 0.5 M and 1.0 M of hydrochloric acid solutions was studied by weight loss method and electrochemical techniques. The inhibition efficiency (eta(w)) increased with an increase in the concentration of NOLE and in temperature. Polarisation curves indicated that NOLE acts as a mixed type of inhibitor. The changes in charge transfer resistance (R-t) with increasing inhibitor (i.e. NOLE) concentration assured the adsorption of the inhibitor onto the metal surface. The results of eta(w), eta(p) (inhibition efficiency obtained from polarisation study) and eta(R) (inhibition efficiency obtained from impedance analysis) are in par with each other. Surface morphology study uncovered the coating of the inhibitor molecule on the metal surface. The phenomenon of physical adsorption has been established based on the inhibition efficiency of the inhibitor with change in temperature.
引用
收藏
页码:387 / 400
页数:14
相关论文
共 21 条
[1]  
Al-Sabagh, 2013, EGYPT J PET, V22, P101, DOI [https://doi.org/10.1016/j.ejpe.2012.09.004, DOI 10.1016/J.EJPE.2012.09.004]
[2]   Corrosion inhibitory properties of elephant grass (Pennisetum purpureum) extract: Effect on mild steel corrosion in 1 M HCl solution [J].
Alaneme, K. K. ;
Olusegun, S. J. ;
Alo, A. W. .
ALEXANDRIA ENGINEERING JOURNAL, 2016, 55 (02) :1069-1076
[3]   Corrosion inhibition and adsorption mechanism studies of Hunteria umbellata seed husk extracts on mild steel immersed in acidic solutions [J].
Alaneme, Kenneth Kanayo ;
Olusegun, Sunday Joseph ;
Adelowo, Oluwabunkunmi Tomi .
ALEXANDRIA ENGINEERING JOURNAL, 2016, 55 (01) :673-681
[4]   Application of electrochemical impedance spectroscopy to study the degradation of polymer-coated metals [J].
Amirudin, A ;
Thierry, D .
PROGRESS IN ORGANIC COATINGS, 1995, 26 (01) :1-28
[5]   2,5-bis(n-pyridyl)-1 3,4-oxadiazoles as corrosion inhibitors for mild steel in acidic media [J].
Bentiss, F ;
Lagrenée, M ;
Traisnel, M .
CORROSION, 2000, 56 (07) :733-742
[6]  
Boudalia M., 2016, Journal of Materials and Environmental Science, V7, P878
[7]  
Callister W. D., 2018, MAT SCI ENG INTRO, DOI DOI 10.1016/0025-5416(87)90343-0
[8]  
Desai P.S., 2015, Int. J. Curr. Microbiol. Appl. Sci., V4, P437
[9]   Corrosion Inhibition and Adsorption Behavior of Some Cationic Surfactants on Carbon Steel in Hydrochloric Acid Solution [J].
Fouda A.S. ;
Migahed M.A. ;
Atia A.A. ;
Mousa I.M. .
Journal of Bio- and Tribo-Corrosion, 2016, 2 (04)
[10]  
Kairi NI, 2013, INT J ELECTROCHEM SC, V8, P7138