Synthesis of biodegradable glycolide/L-lactide copolymers using iron compounds as initiators

被引：79
作者：
Dobrzynski, P [1 ]
Kasperczyk, J [1 ]
Janeczek, H [1 ]
Bero, M [1 ]
机构：
[1] Polish Acad Sci, Ctr Polymer Chem, PL-41819 Zabrze, Poland
来源：
POLYMER | 2002年 / 43卷 / 09期
关键词：
glycolide; lactide; iron compounds;
D O I：
10.1016/S0032-3861(02)00079-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The aim of this paper is to present a new method of copolymerization of glycolide with L-lactide with the use of low toxic iron compounds. The use of Fe(acac)(3) and Fe(OEt)(3) initiators enabled one to obtain copolymers with yields up to 100% and possessing good mechanical properties. The chain propagation process and the influence of the transesterification was examined. On the basis of NMR examination and DSC thermograms, it was shown that the samples obtained at the temperature of 100 degreesC with the use of the initiators have quasi-segmental chain microstructure. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2595 / 2601
页数：7
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